19 Quantum Physics Flashcards

(23 cards)

1
Q

Definition of a Photon

A

A quantum of electromagnetic energy

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2
Q

Energy of a Photon formula

A

E = hf
Where h is Planck’s constant, f is frequency

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3
Q

Electronvolt eV to Joules J conversion

A

1 eV = 1.60 x10^-19 J

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4
Q

What is the photoelectric effect?

A

The emission of electrons from a metal surface when the surface is irradiated with electromagnetic radiation of a high enough frequency

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5
Q

What is stopping potential (Vs)?

A

The value of potential difference where detected photocurrent just becomes zero
E(k, max) = e(Vs)

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6
Q

Evidence of the particulate nature of light from the photoelectric effect

A

Instantaneous emission of photoelectrons -> photon-electron interaction is one-to-one

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7
Q

Einstein’s photoelectric effect relation

A

hf = ϕ + E(k, max)
Energy of photon = work function + max E(k) of electron

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8
Q

Effect on changing frequency on photocurrent

A

As frequency increases, the stopping potential increases in magnitude (more negative)
Photocurrent remains constant

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9
Q

Effect of changing intensity on photocurrent

A

As intensity increases, maximum photocurrent increases
Stopping potential remains constant

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10
Q

de Broglie Wavelength equation

A

λ = h/p
Where p is momentum

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11
Q

Heisenberg Uncertainty Principle

A

ΔpΔx ≈ h
ΔpΔx must be in the same direction (usually at the slit)

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12
Q

Ground state of an atom

A

The lowest state an atom can be at where all electrons in the atom occupy the lowest possible energy states

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13
Q

Excited state of an atom

A

When one or more electrons of an atom are not occupying the lowest possible energy state

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14
Q

Ionisation

A

The removal on an electron from an atom to create an ion

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15
Q

What is an emission line spectrum?

A

A series of distinct coloured lines against a dark background

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16
Q

What is an absorption line spectrum?

A

A series of distinct dark lines against a continuous background

17
Q

Number of emission lines

A

n choose 2, where n is number of energy states

18
Q

Number of absorption lines

A

n -1, where n is number of energy states

19
Q

Characteristics of an X-ray spectrum

A
  • Broad continuous spectrum (Braking radiation)
  • Sharp peaks (Characteristic lines)
  • Sharp cut-off (Minimum wavelength)
20
Q

How is Braking Radiation produced?

A
  • External electrons does not collide with internal electrons
  • The electron instead experiences an acceleration, deceleration or deflection, which emits braking radiation
21
Q

How is characteristic X-ray lines formed?

A
  1. Accelerated incident electron collides with an electron from the innermost shell.
  2. Inner electron is kicked out
  3. An electron from a higher energy shell transitions to the vacant spot, which emits a photon
22
Q

Why is there a sharp cut-off at the end of the x-ray spectrum?

A
  • X-ray photon with the maximum energy is emitted when all E(k) of electron is transferred
  • Thus, there is a maximum frequency of photons, which means there is a minimum wavelength of the photon
23
Q

Why is the energy levels of an atom negative?

A

Electrical potential energy is defined to be 0J when it is at infinity. Since electrons are attracted to nucleus, work is done against the electron in order to bring the electron from infinity to the point