2.1.1 ATomic Structure & Isotopes Flashcards

(18 cards)

1
Q

What are the three main subatomic particles in an atom?

A

Proton, neutron, electron

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2
Q

What is the relative mass and relative charge of proton, neutron, and electron?

A

Proton: relative mass = 1, relative charge = +1
Neutron: relative mass = 1, relative charge = 0
Electron: relative mass = 1/2000, relative charge =-1

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3
Q

Where is the mass of an atom. Mostly concentrated? Why?

A

In the nucleus, because protons and neutrons are located there and electrons have negligible mass.

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4
Q

Define atomic number

A

Number of protons in the nucleus of an atom.

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5
Q

Define mass number

A

Total number of protons + neutrons in he nucleus.

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6
Q

What is an isotope?

A

Isotopes are atoms of the same element but different numbers of neutrons, and thus different mass numbers.

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7
Q

Do isotopes have the same chemical properties?

A

Yes, because they have the same number of electrons and the same electron configuration, so their chemistry (bonding) is identical.

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8
Q

Do isotopes have the same physical properties?

A

No, because their masses differ so physical properties vary.

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9
Q

Define relative isotopic mass

A

The mass of a particular isotope compared t the 1/12th of the mass of one atom of carbon-12.

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10
Q

Write the formula to calculate relative atomic mass given isotopic masses and abundances.

A

(Mz X %) over 100.

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11
Q

What is a mass spectrometer used for in this topic?

A

To find isotopic masses and relative abundances of isotopes in a sample, which allow calculation of relative atomic mass.

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12
Q

Outline the main steps in a mass spectrometer.

A
  1. Ionisations- sample atoms are ionised to form positive ions.
  2. Acceleration- ions are accelerated by electric fields.
  3. Deflection- an applied magnetic field deflects ions; degree of deflection depends on mass/charge ratio.
    4.detection- ions hit a detector, producing a signal; relative heights correspond to abundence.
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13
Q

What is mass spectrum? What do the axes represent?

A

A graph with masses (m/z or isotopic mass) on the x axis and relative abundance on the y axis. Peaks correspond to isotopes present.

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14
Q

How would you use mass spectrometry data in an exam to find Ar?

A

Identify the masses of isotopes, their relative abundance, convert abundence to. Percentages, then use the weighted average formula.

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15
Q

Define relative molecular mass

A

The sum of relative atomic masses of all atoms in a molecule.

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16
Q

Define relative formula mass

A

For ionic compounds, is the sum of the relative atomic masses of all ions in its formula unit.

17
Q

Why do relative masses have no units?

A

Because they are ratios comparing to a standard 1/12 of a carbon 12 atom, thus they are dimensionless.

18
Q

What is the diference between an atoms mass number and to relative isotopic mass?

A

Mass number is a whole number= protons + neutrons. Relative isotopic mass is a mass on. The relative scale. Compare to 12 carbon atom