29- polymerisation Flashcards

(13 cards)

1
Q

what is a condensation reaction

A

when two molecules react together and a small molecule of water or hydrogen chloride is eliminated

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2
Q

what is the polyester linkage

A

the ester linkage -COOH-

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3
Q

how are polyesters made

A

by reacting diols and dicarboxylic acids

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4
Q

what is the polyester terylene made from

A

benzene-1,4-dicarboxylic acid and ethane-1,2-diol

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5
Q

how are polyamides formed

A

when an diaminoalkane and a dicarboxylic acid react together

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6
Q

what is the polyamides linkage

A

amide linkage -CONH-

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7
Q

how is nylon-6,6 formed

A

it is made from 1,6-diaminohexane and hexane-1,6-dicarboxylic acid

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8
Q

how do you speed up the formation of nylon-6,6

A

you use diacid chloride instead of the dicarboxylic acid, in this case hydrogen chloride is eliminated

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9
Q

how do you form kevlar

A

by reacting benzene-1,4-diamine and benzene-1,4-dicarboxylic acid

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10
Q

what makes kevlar to strong

A

the rigid chains and the ability of the flat aromatic rings to pack together held by strong intermolecular forces

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11
Q

how are poly(ethane) and poly(propene) disposed of

A

usually in landfill sites or by incineration
some may be melted down and remolded

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12
Q

how are poly(alkenes) disposed of

A

they can be burnt to carbon dioxide and water to produce energy, although poisonous CO may be released due to incomplete combustion

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13
Q

how are condensation polymers like polyesters and polyamides disposed of

A

they can be broken down by hydrolysis

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