2b Flashcards

(29 cards)

1
Q

what is oxidation

A

conversion of a functional group in another one with a higher oxidation state or level

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2
Q

reduction

A

conversion of a functional group in another one with a lower oxidation level or state

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3
Q

reduction does what to an oxidation level

A

reduces the value
the value gets smaller

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4
Q

what does oxidation do to an oxidation level

A

increases the oxidation level or state

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5
Q

what is a heteroatom

A

anything but a C or H

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6
Q

how many levels of oxidation levels/states are there

A

5 in total
0,1,2,3,4

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7
Q

whats a 0 oxidation level

A

carbons are bonded to 0 more electronegative atoms

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8
Q

level 0 oxidation level examples

A

methane
alkanes

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9
Q

what is level 1 oxidation level

A

C is bonded to 1 more electronegative element

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10
Q

level 1 oxidation state examples

A

alkene
alcohol
halogenoalkanes

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11
Q

level 2 oxidation level

A

carbon is bonded to 2 more electronegative atoms

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12
Q

level 2 oxidation level examples

A

ketone
alkyne (c triple c)
aldehyde

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13
Q

level 3 oxidation level

A

carbon bonded to 3 more electronegative elements

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14
Q

levels 3 oxidation level examples

A

carboxylic acid
amides
nitriles

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15
Q

level 4 oxidation level

A

carbon is bonded to 4 more electronegative elements

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16
Q

level 4 oxidation level examples

17
Q

resonance structure rules

A
  • have the same number of valence electrons
  • octet rule must be obeyed
  • nuclei do not change positions in space between resonance structures
18
Q

what do resonance structures differ in

A

they differ in the arrangement of valence electrons

19
Q

what is special about c=o

A

the c and o are electrophilic and basic respectively.

c is electrophilic
o is basic

20
Q

what does the c react with

A

nucleophiles bc it has a partial positive charge

21
Q

what does the o react with

A

lewis acids

things that accept electrons

22
Q

if o interacts with lewis acids it must be a

A

weak lewis base
donates electrons

23
Q

what is the alpha carbon

A

the carbon next to the carbonyl group

the carbon near the c=o

24
Q

the alpha carbon is usually bonded to what

A

the carbonyl group
alpha Hydrogens

25
what are special about alpha Hydrogens
theyre bonded to the alpha carbon they are more acidic than alkane hydrogens
26
removal of the alpha hydrogens via deprotonation will give what
it will give an anion (-)
27
deprotonation of a alpha hydrogen will give an anion,, how can these be stabilised
through delocalisation aka resonance? the (-) formed by protonation is delocalised over the pi system (c=o) and is ultimately placed on the more electronegative Oxygen atom
28
what shape is c=o
its planar
29