Fe2+
Add dilute NaOH to the solution. A dirty green ppt. will form.
Fe3+
Add dilute NaOH to the solution. A reddish-brown ppt. will form.
Al3+
In two separate test tubes, add NaOH and NH3 to the solution. A white ppt will form. It is soluble in excess NaOH but not excess NH3.
Ca2+
In two separate test tubes, add NaOH and NH3 to the solutions. White ppt. will form in NaOH and a little white ppt / no at all will form in NH3. Both insoluble in excess.
Zn2+
In two separate test tubes, add NaOH and NH3 to the solution. White ppt will form and both soluble in excess.
Cu2+
Add NaOH to the solution. It will form light blue precipitate.