What does the First Law of Thermodynamics state for a closed system?
The change in internal energy equals the work done on the system plus the heat added to the system (ΔE = ΔW + ΔQ).
What is the infinitesimal work done by a gas during expansion?
dW = -p dV.
What is the per-unit-mass form of the First Law of Thermodynamics?
de = -p d(1/ρ) + δq.
What is the ideal gas law in terms of density?
p = ρRT / MW.
What does MW represent in the ideal gas law?
The molecular weight of the gas.
What is the formula for internal energy of a calorically perfect gas?
e = c_v T.
What is c_v?
Specific heat at constant volume.
How is enthalpy defined for a system?
H = E + pV.
How is specific enthalpy defined per unit mass?
h = e + p/ρ.
What is the enthalpy of an ideal gas in terms of temperature?
h = c_p T.
What is the relation between c_p and c_v?
c_p = c_v + R/MW.
What is the definition of the specific heat ratio γ?
γ = c_p / c_v.
What is the approximate value of γ for air?
γ = 1.4.
What is an adiabatic process?
A process in which no heat is transferred (ΔQ = 0).
What is a reversible process?
A process that occurs slowly enough to maintain thermodynamic equilibrium and can be reversed.
What is the temperature-density relation for an isentropic ideal gas process?
T/T₀ = (ρ/ρ₀)^(γ−1).
What is the temperature-pressure relation for an isentropic ideal gas process?
T/T₀ = (p/p₀)^((γ−1)/γ).
What makes shock waves irreversible?
They generate entropy and destroy isentropic behavior.
When do isentropic relations fail?
In the presence of shock waves.
What is the entropy change for reversible heat transfer?
dS = δQ/T.
What is the per-unit-mass entropy relation?
ds = δq/T.
What is the fundamental thermodynamic identity involving entropy?
T ds = de + p d(1/ρ).
What is an isentropic process?
A reversible adiabatic process with constant entropy.
What is the total energy per unit mass of a moving fluid?
e + u²/2.