Chapter 22 Flashcards

(14 cards)

1
Q

Writing the acid and base catalyzed tautomerization either from enol to a keto form/vise versa

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2
Q

Converting keto to enol/vise versa

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3
Q

Predict products of an enol w/ a halogen leading to substitution under acidic conditions.

A
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4
Q

Predict products for the formation of a a,b-unsaturated carbonyl

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5
Q

Identify the acidities of hydrogens on a-carbons of various carbonyl species

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6
Q

Rank the acidities of hydrogens on a-carbons of various carbonyl species

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7
Q

Write mechanism of racemization reaction that occurs from enolization

A
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8
Q

Predict products and write mechanism of base promoted alkylation reactions of various enolates including direct alkylation

A
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9
Q

Predict products and write mechanism of base promoted alkylation reactions of various enolates including Malonic ester synthesis

A
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10
Q

Predict products and write mechanism of base promoted alkylation reactions of various enolates including acetoacetic acid synthesis

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11
Q

Write reaction of an enol w/ a halogen leading to substitution under acidic conditions.

A
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12
Q

What is the first step of Mechanism for acid catalyzed isomerization

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13
Q

Predict the precursor of the reagents to accomplish acetoacetic synthesis

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14
Q

Predict the precursor of the reagents to accomplish malonic ester synthesis

A
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