What is a composite material?
2 or more constituent materials with different physical or chemical properties that when combined, produce a material with characteristics different from the individual components
What are some examples of composites in the human body?
Enamel, dentin, bone, muscle, cells
What is resin composite?
Reinforced polymer used for restoring enamel and dentin
What is the correct term for composite resin?
Polymer matrix composite or Particular-reinforced polymer matrix composite
How are composites classified?
By particle size and percent distribution of inorganic filler
What types of composites are best for restorative procedures?
Microfilled - best esthetics, good finish, continued smoothness, lacks strength; Hybrid - Good esthetics and strength - lacks long term smoothness
What were the first polymeric direct restorative material?
Silicates in 1878
What is acrylic restorative resin?
Unfilled, low molecular weight polymers without reinforcing filler particles
What about composites made them better than acrylic restorative resin?
Improved physical properties (i.e. lower coefficient of thermal expansion)
In multipurpose composites, what are the 4 major components?
What are the organic polymer matrix materials that are common in multi-purpose composites?
Dimethacrylates (Bis-GMA), Urethane dimethacrylate (UDMA)
What are the inorganic filler particles used in multipurpose composites?
What is the most common coupling agent?
Silane (organosilane) KNOW THIS
What does silane do in multipurpose composites?
Acts as a coupling agent that binds the inorganic filler particles to the organic matrix; Forms a homopolymer film on the surface of the filler; Bond degrades in contact with water intraorally
What are some common initiator-accelerator systems used in multipurpose composites?
how can the material set Hannah
Chemical cure, light cure, or dual cure
By what reaction do resin monomers undergo to harden?
Free radical polymerization
What is free radical polymerization inhibited by?
Oxygen - leaves a soft sticky surface, or oxygen inhibited layer
What is the weakest part of a composite resin?
Matrix - needs filler particles
If you have more filler, what happens?
Material is stronger and more abrasion resistant; Greater resistance to wear!
If a composite has no filler, it is called _____________________. If it does have filler particles, it is called a ______________________.
Unfilled resin, filled resin
What is the function of the filler?
To reinforce the resin matrix, provide the appropriate degree of translucency, and control the volumetric shrinkage during polymerization
What are some common classifications of filler?
Microfilled, Microhybrids, Nano hybrids
What is free radical polymerization?
Chain reaction requiring free radicals from either a chemical cure or a diketone-amine system in visible blue light; 3 stages; Inhibited by oxygen
What are the three steps of free radical polymerization reactions?
Initiation, propagation, termination