Resin modified GIs, GI
hydrophobic (water based)
self-adhesive
no adhesive required
Compomers, Composite resin
hydrophobic (resin based)
Not self adhesive - requires adhesive
Dental composite matrix phase
continuous phase
dental composite dispersed phase
discontinuous phase
Monomer functional groups
monomethacrylates
dimethacrylates
monomethacrylates
linear chains - soft - can melt easily
dimethacrylates
branched and crosslinked - rigid, don’t melt easily.
Composite monomers
difunctional methacrylates
form highly crosslinked rigid networks
Monomers in composite
potentially estrogenic - tegma, BIS-GMA, TEGDMA
Silicate glasses influence
strengthen (rule of mixtures, more filler = more strength) Optical properties (color, translucency) Radiopacity
Filler surface
glass has hydrophilic surface
Silane coupling agent
silane coupler - gets hyrophilic glass into composite
Abrasive
non-contact wear - foods abrade polymer
Attrition
occlusal contact wear - higher stresses, lead to polymer microfracture
Improved wear from
smaller, softer particles
Crystalline (original) filler
quartz - radiolucent, very hard and abrasive
Non-crystaline (glasses)
modified to improve characteristics
-softer, additives to make glass radiopaque, more crushable, need to have it wear with resin**
GI
acid base rxn
Composites
free radical rxn
Dentin as substrate
initial preps likely to encounter tubular dentin
Smear layer inhibits good adhesion
ground bits of HA, collagen, bacteria, salivary proteins Inhibits resin penetration into dentin
Etchant
inorganic acid - 35% Phosphoric acid
completely remove smear layer and plugs
demineralizes surface dentin
leaves a collagen rich surface with numerous pores
Primer
primarily hydrophilic monomers - water, alcohol, acetone barrier
Adhesive
hydrophilic/hydrophobic mix