atoms form covalent bonds by sharing pairs of electrons, meaning they both have full outer shells.
strong electrostatic attraction between negative shared electrons and positive nuclei of atoms involved
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2
Q
simple molecular substances
A
atoms within a molecule are held together by very strong covalent bonds
the forces of attraction between the molecules are very weak
this means melting and boiling points are very low because the molecules are easily separated
mostly gases or liquids at room temp
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3
Q
Giant covalent structures
A
all the atoms are bonded to each other by STRONG COVALENT BONDS
there are lots of bonds which means it takes a lot of energy to break them, so giant covalent structures are SOLIDS with VERY HIGH MELTING AND BOILING POINTS
DONT conduct electricity (except graphite)
insoluble in water
eg diamond and graphite
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4
Q
diamond
A
carbon atoms with 4 covalent bonds
high melting point = hard to break covalent bonds
rigid lattice structure = very hard
doesn’t conduct electricity as no free electrons or ions
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5
Q
graphite
A
each carbon atom only forms 3 covalent bonds, creating layers of carbon atoms. the layers are only held together weakly by intermolecular forces so are free to slide over each other = soft and slippery
high melting point = strong bonds within the layers
conducts electricity = one delocalised electrons that can conduct electricity
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6
Q
C60 fullerene
A
hollow spheres of 60 carbon atoms
not a giant covalent structure just made up of large covalent molecules
only held together by intermolecular forces so can slide over each other = soft
does have a delocalised electron but it cannot move between molecules so it’s a poor conductor of electricity