Pericyclic > Cycloaddition > Flashcards

Cycloaddition Flashcards

(8 cards)

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1
Q

Types of cycloaddition rxn (4+2)

A

DARxn
1,3 bipolar cycloaddition rxn
Chelotropic ( diene + do2)
Allylic c+ + diene

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2
Q

DAR
Diene + dienophile

A

HOMO + LUMO

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3
Q

Even electron pair

A

Light

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4
Q

Special dienes

A

Benzene ring ke 2 carbon ko hata kr nitrogen add Kar DE

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5
Q

Reactivity of diene

A

Electron density more Reactivity more

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6
Q

Reactivity of dienophile

A

Electron density less reactivity more

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7
Q

Reactivity of dienophile

A

Electron density less reactivity more

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8
Q

TBAF

A

Tetra butyl N+F-
Deprecating agent

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