DAY BEFORE THERMAL PHYSICS Flashcards

(23 cards)

1
Q

what is meant by internal energy

A
  • the sum of randomly distributed potential and kinetic energies of particles in a body
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2
Q

how can internal energy be increased

A
  • doing work on system
  • adding thermal energy to it
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3
Q

how can internal energy be decreased

A
  • losing thermal energy to surroundings
  • system doing work on surroundings
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4
Q

whats the 1st law of thermodynamics

A

“internal energy of a system can be increased when energy is transferred to it by heating or when work is done on it”

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5
Q

explain compressing the gas

A
  • work being done ON gas
  • internal energy of particles increases
  • particles have a greater average KE
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6
Q

explain gas expanding

A
  • work being done BY gas ON surroundings
  • internal energy of gas decreases
  • average KE of particles decreases
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7
Q

define specific heat capacity

A
  • the amount of thermal energy required to change the temperature of 1kg of a substance by 1K, without changing state
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8
Q

define specific latent heat

A

the amount of thermal energy required to change the state of 1kg of a substance without changing temperature

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9
Q

whats equation for continious flow rate for c

A

Q2 - Q1 / ( m2 - m1) delta temp

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10
Q

define specific latent heat of fusion
define specific latent heat of vaporisation

A
  • thermal energy required to convert 1kg of a solid into a liquid, without change in temp
  • thermal energy required to convert 1k of a liquid into a gas, without a change in temp
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11
Q

explain the slopes and flats on a T - I graph

A

slopes : temp is changing as we reach temp for melting / evaporation, average KE of particles increases

flats : temp constant, but bonds break/ form so potential energy increases

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12
Q

define absolute zero

A
  • temp at which molecules have 0 kinetic energy
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13
Q

whats Boyle’s Law

A

at a constant temp, pressure inversely proportional to volume

p1v1 = p2v2

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14
Q

whats Charle’s Law

A

at a constant pressure, volume is proportional to temperature

v1/t1 = v2/t2

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15
Q

whats pressure law?

A
  • at a constant volume, pressure is proportional to temperature

p1/t1 = p2/t2

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16
Q

what an ideal gas

A

gas that obeys pV ~ T

17
Q

why high temp high pressure

A
  • temp is a measure of average KE of particles
  • temp ~ KE
  • increasing temp increases velocity of particles
  • change in momentum is greater hence force greater
  • pressure is force per unit area, pressure increases
18
Q

why smaller volume higher pressure

A
  • smaller volume means particles collide more frequently
  • pressure is force per unit area
  • more force ( due to change in momentum ) hence more pressure
19
Q

work done by a gas?

A

pressure x change in volume

20
Q

equations for ideal gases

A

pV = nRT
pV = NkT

21
Q

whats internal energy for an ideal gas?

A

U = N x Ek

as no intermolecular forces

22
Q

how to calculate molar mass

A

mass / number of moles

23
Q

what are assumptions for derivation?

A
  • no intermolecular forces
  • time of collision is negligible compared to time between
  • volume or molecule negligible compared to container
  • elastic collisions