Granitoid composition
Siliceous feldspathic rocks
Essential quartz, plagioclase and alkali feldspar
Granite = albite, oligoclase & orthoclase and microcline
Diorites and granodiorites have variable felsic compositions but lots of mafic minerals such as pyroxenes, hornblende, micas, plus reasonably abundant titanite, apatite etc (these only found in granites intrace amounts)
Sensu stricto?
In the strict sense/ Using the most precise, literal, or limited definition of a term
accessory minerals from hydrothermal processes in granitoids
Tourmaline (B), topaz (F); almandine (Fe); spessartine (Mn); epidote, allanite.
Sulphides and oxides of base and occasionally precious metals:
Cu-Ni-Fe-Zn-Pb-Sn-As-Au-Ag etc.
Iron oxide depending on ƒO2:
Magnetite, hematite.
Others:
Fluorite, barite. OPX in charnockite (high-T anhydrous granite)
Granitoid textures
Megacrystic (aligned) granite
Igneous layering in granodiorite
Rapakivi texture: plagioclase over k-spar (- coarse, early oligoclase mantle around orthoclase core)
-> solid solution becomes unstable.
- The plagioclase component (oligoclase) unmixes first because it is the least soluble at high T.
Mafic enclaves in granodiorite (mafic blobs in otherwise felsic matrix)
Granophyric texture
fine-grained, microscopic igneous rock texture characterized by the intimate, often radiating, or angular intergrowth of quartz and alkali feldspar
Looks like zebra stripes but stripes disconnected
Quartz resoprtion
quartz phenocrysts in magma are partially dissolved or corroded by the surrounding melt (change environmental conditions, such as temperature, pressure, or chemical composition)
Granitoid textures in thin section?
Quartz resorption
Granophytic texture
Crystallisation order in granitoids
Not easy to determine
accessory phases appear first: zircon, apatite, titanite ~650-700oC
Followed by plag + mafics: hornblende, biotite.
Quartz & alk feldspar as late interstitial phases
Variables: bulk comp, P, T, O2%, H2O%
H2O faciliitates
Nucleation
Nucleation = the formation of new crystal seeds
melt contains a lot of dissolved H₂O:
-> melt structure becomes more depolymerised (more “fluid” at atomic scale)
-> energy barrier for forming a stable crystal nucleus increases.
-> fewer crystals nucleate, and they nucleate later.
why pegmatites don’t have millions of tiny crystals—they don’t nucleate readily
H2O impact on crystal nucleation and growth
melt contains a lot of dissolved H₂O:
-> melt structure becomes more depolymerised (more “fluid” at atomic scale)
-> energy barrier for forming a stable crystal nucleus increases.
-> fewer crystals nucleate, and they nucleate later.
why pegmatites don’t have millions of tiny crystals—they don’t nucleate readily
Once crystal nucleus does form, H₂O:
- It dramatically increases ion mobility.
- It lowers melt viscosity.
- It enhances diffusion of Si, Al, Na, K, Ca.
So nuclei that exist can grow extremely fast and to very large sizes.
More in depth IUGS silica classification
INTERMEDIATE: 52 – 63 wt %.
52 – 57 wt % gabbroids (basaltic andesite)
57 – 63 wt % diorites (andesites)
ACID: 63 - >77 wt %.
63 – 77 wt % granodiorites (dacites)
>77 wt % granites (rhyolites)
Aliminium saturation of granitoids
Granitoid rocks also classified through Aluminum proportions relative to CaO, K2O & Na2O (these feldspar elements are classed as one group)
Groups are Peraluminous, Metaluminous & Peralkaline
Specify Peraluminous, Metaluminous & Peralkaline
Peraluminous = Greater Al% than feldspar elements
Biotite,Muscovite,cordierite,Andalusite,Garnet
Metaluminous = Similar Al% to feldspar elements
Pyroxene, hornblende, biotite
Peralkaline = Lesser Al% than feldspar elements
Mostly Alkali amphiboles and pyroxenes (Aegirine, Riebeckite & Afvredsonite)
Occurance and distribution
Granitoid origins
Composition implies derivation from crustal anatexis (partial melting)
Composition of crust varies
f means fugacity
Meaning availability of element to react in solution
crystallisation order impact on euhedral/sub/anhedral
As more crystals form there is a fight for space resulting in other minerals either losing space and becoming sub-anhedral rather than euthedral
Cant distinguish between igneous and mantle rocks down the microscope so in exam say I/M
Pneumatolysis
Pneumatolysis is the alteration of rocks or magmas by high temperature volatile rich fluids -e.g. gaseous phases released from cooling magma
Greisenisation: Feldspar replaced by quartz and muscovite.
Tourmalinisation: Essentially converting granite to quartz and tourmaline.