Enthalpy Changes Flashcards

(14 cards)

1
Q

Standard Conditions for enthalpy changes

A

100KPa
Speciefied temp (298K)

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2
Q

What is the standard enthalpy of formation

A

The enthalpy change when 1 mole of the compound is for,ed form its elements in standard states and conditions

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3
Q

What is the standard enthalpy of combustion

A

The enthalpy change when 1 mole of a substance is completely burned in oxygen under standard conditions

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4
Q

What is the standard enthalpy of neutralisation

A

The enthalpy hange when an acid and an alkali react to form 1 mole of water under standard conditions

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5
Q

What is bond breaking

A

Endothermic

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6
Q

What is bond making

A

Exothermic

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7
Q

Equations for enthalpy changes

A

q=m c deltaT
M=volume in grams
Delta T= change in temp
q= heat lost or gained in joules
DeltaH = q/n
Remember to add in positive or negative sign at the end

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8
Q

Describe what is meant by activation energy

A

The minimum amount of energy particles must collide with in order for the reaction to occur

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9
Q

Describe a Exothermic graph

A

Reactants higher than products
Activation energy from reactants to top of hill
Delta H from reactants to products

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10
Q

Describe an endothermic graph

A

Reactants lower then products
Activation energy from reactants to top of hill
Delta H from reactants to products

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11
Q

Define enthalpy change

A

The heat added to the system under constant pressure
Enthalpy change = enthalpy of products- enthalpy of reactants

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12
Q

Describe the Hess cycle for enthalpies of formation

A

Y shape both arrows come from elements to reactants/products
Times given values by molar quantity

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13
Q

Describe Hess cycle for enthalpy of combustion

A

Both arrows come into the intermediate
take into account molar quantities

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14
Q

Describe Hess cycle for bond enthalpies

A

Both arrows come into the intermediate

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