What is thermodynamics?
Branch of physical chemistry focusing on energy in a chemical system: reactants and products
What can energy be changed into?
Different types of energy
How must chemists carry out meaningful calculations?
All values must be measured under standard conditions
What are standard conditions?
• 100 kPa/1 bar
• 298°K/25°C
• Given plimsoll line symbol (⦵)
What does it mean that all substances are in their standard states?
In most stable form
What is the enthalpy change of a reaction?
Energy change associated with a given reaction
What does a thermodynamic equation include?
Both balanced chemical equation and enthalpy data
What is enthalpy change of formation?
Energy change taking place when 1 mole of a compound is formed from its constituent elements in their standard state under standard conditions
What may you need to do when writing a thermodynamic equation?
Use fractions to balance equation, as you must ensure there’s only 1 mole of product
What is the standard enthalpy change of formation of an element in its standard states?
0 kJ mol⁻¹
Why is the standard enthalpy change of formation of an element in its standard states 0 kJ mol⁻¹?
According to definition there’s no change (as no compound is formed), so no energy is released or taken in
What is enthalpy change of combustion?
Energy change taking place when 1 mole of a substance is completely combusted
What is enthalpy change of neutralisation?
Energy change associated with formation of 1 mole of water from a neutralisation reaction