Alkane
C–C single bonds only. Suffix: –ane.
e.g. CH₄ (methane).
Alkene
Contains C=C double bond. Suffix: –ene.
e.g. CH₂=CH₂ (ethene).
Alkyne
Contains C≡C triple bond. Suffix: –yne.
e.g. CH≡CH (ethyne).
Haloalkane/halogeno
Contains C–X (X = F, Cl, Br, I).
e.g. CH₃Cl (chloromethane).
Hydroxyl (Alcohol)
Contains –OH group. Suffix: –ol.
e.g. CH₃CH₂OH (ethanol).
Alkoxy (Ether)
Contains C–O–C linkage. Name: alkoxy- (e.g. methoxyethane).
Shorter chain always the oxy
Carbonyl (Aldehyde)
–CHO (C=O at end of chain). Suffix: –al.
e.g. CH₃CHO (ethanal).
Carbonyl (Ketone)
C=O within chain (not terminal). Suffix: –one.
e.g. CH₃COCH₃ (propanone).
Carboxyl (Carboxylic acid)
–COOH (C=O and –OH on same C). Suffix: –oic acid.
e.g. CH₃COOH (ethanoic acid).
Ester
–COO– (derived from acid + alcohol). Suffix: –oate.
e.g. CH₃COOCH₃ (methyl ethanoate).
Side with carbon double bond to oxygen is the oate.
Amide/Amido
–CONH₂ (carbonyl + amine). Suffix: –amide.
e.g. CH₃CONH₂ (ethanamide).
Amino (Amine)
–NH₂ (basic group). Prefix: amino– or suffix: –amine.
e.g. CH₃CH₂NH₂ (ethylamine).
Phenyl (Benzene ring)
C₆H₅– group. Aromatic ring (π delocalisation).
e.g. C₆H₅CH₃ (methylbenzene).