Isotopes Flashcards

(32 cards)

1
Q

Q: What is an isotope?

A

A: Atoms of the same element with the same number of protons but different numbers of neutrons, resulting in different mass numbers.

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2
Q

Q: Why do isotopes of the same element have similar chemical properties?

A

A: Because chemical behaviour depends on electron configuration and proton number, which are identical for isotopes of the same element.

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3
Q

Q: Why can isotopes have different physical properties?

A

A: Because they have different masses due to different numbers of neutrons, affecting properties such as density and diffusion rate.

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4
Q

Q: Why does 1 mole of Li-6 have a different mass than 1 mole of Li-7?

A

A: Because isotopes differ in neutron number, changing their atomic mass.

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5
Q

Q: What determines nuclear stability?

A

: The balance between:

Strong nuclear force (attractive between nucleons)

Electrostatic repulsion (between protons)

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6
Q

Q: Why are stable isotopes not radioactive?

A

A: Their strong nuclear force balances proton–proton repulsion, creating a stable nucleus.

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7
Q

Q: Why are unstable isotopes radioactive?

A

A: Because the attractive and repulsive nuclear forces are unbalanced, making the nucleus unstable.

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8
Q

Q: Why is there a limit to how large a nucleus can grow?

A

A: Electrostatic repulsion increases with proton number, eventually overpowering the strong nuclear force.

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9
Q

Q: What is radioactive decay?

A

A: A spontaneous process where an unstable nucleus emits particles or radiation to achieve stability.

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10
Q

Q: What is transmutation?

A

A: The transformation of one element into another due to radioactive decay.

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11
Q

Q: What happens in alpha decay?

A

A: The nucleus emits an alpha particle (²⁴He nucleus).
Mass number decreases by 4, atomic number decreases by 2.

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12
Q

: What occurs in beta-minus decay?

A

A neutron converts into a proton, emitting:

An electron

An antineutrino
Atomic number increases by 1.

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13
Q

What occurs in beta-plus decay?

A

A proton converts into a neutron, emitting:

A positron

A neutrino
Atomic number decreases by 1.

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14
Q

What occurs in gamma decay?

A

: An excited nucleus releases energy as a gamma photon without changing mass or atomic number.

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15
Q

What is half-life?

A

The time required for half of a radioactive sample to decay.

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16
Q

Why must medical isotopes have short half-lives?

A

o minimise radiation exposure while still allowing imaging.

17
Q

Q: What is mass number?

A

A: Number of protons + neutrons.

18
Q

Q: How do you calculate neutrons?

A

A: Neutrons = Mass number − Atomic number.

19
Q

Q: What does ³⁷Cl mean?

A

: Chlorine isotope with mass number 37 (17 protons, 20 neutrons).

20
Q

Q: Why is relative atomic mass usually not a whole number?

A

A: Because it is a weighted average of all naturally occurring isotopes.

21
Q

Q: How do you calculate RAM?

A

RAM = Σ (isotope mass × fractional abundance)

22
Q

Why are hydrogen isotopes unique?

A

They have special names and show large mass differences relative to proton number.

23
Q

Q: What is protium?

A

A: ¹H — 1 proton, 0 neutrons — most abundant (~99.98%).

24
Q

Q: What is deuterium?

A

A: ²H — 1 proton, 1 neutron — used in NMR and heavy water (D₂O).

25
Q: What is tritium?
A: ³H — 1 proton, 2 neutrons — radioactive, half-life 12.32 years.
26
Q: What does a mass spectrometer measure?
A: The mass-to-charge ratio (m/z) of ions.
27
What are qualitative uses of mass spectrometry? A:
Identifying compounds Determining isotopic composition Structural analysis
28
Q: What are quantitative uses of mass spectrometry?
A: Measuring concentration of substances in a sample.
29
Q: What is the first step in mass spectrometry?
A: Ionisation — gas particles are ionised by an electron beam.
30
Q: What happens after ionisation?
A: Ions are accelerated by an electric field.
31
Q: What happens in the magnetic field?
A: Ions are deflected based on mass: Lighter ions deflect more Heavier ions deflect less
32
What does the detector measure?
: The number of ions hitting it, determining relative abundance.