what is meant by Kc?
the equilibrium constant
what is the Kc equation?
concentration of products / concentration of reactants
what does it mean if Kc is higher than 1?
there is a higher product concentration than reactant concentration so equilibrium lies to the right (products)
what does it mean if Kc is lower than 1?
there is a higher reactant concentration than product concentration so equilibrium lies to the left (reactants)
why do we need to be careful with heterogenous reactions in the Kc equation?
liquid/solid concentrations remain constant so are left out of the equation
what do you do if a Kc calculation gives you the equilibrium concentrations?
substitute into the equation
what do you do if a Kc calculation gives you the equilibrium moles and the volume?
moles / volume to work out concentrations
then substitute into equation
what do you do if a Kc calculation gives you the initial moles and equilibrium moles of either a product or reactant?
use an ICE table
describe how an ICE table works
what factor affects the value of Kc?
temperature
what happens to the value of Kc if temperature is increased in an EXOTHERMIC reaction? why?
decreases
- concentrations need to change to establish a lower equilibrium
- products decrease, reactants increase
- equilibrium shifts left (in endothermic direction)
what happens to the value of Kc if temperature is increased in an ENDOTHERMIC reaction? why?
increases
- concentrations need to change to establish a higher equilibrium
- products increase, reactants decrease
- equilibrium shifts right (in endothermic direction)
what happens to the POSITION OF EQUILIBRIUM if the concentration of reactants increases?
shifts right
- increases product conc
- decreases reactant conc
what happens to the POSITION OF EQUILIBRIUM if the concentration of products increases?
shifts left
- decreases product conc
- increases reactant conc