Kinetics Flashcards

(27 cards)

1
Q

Activation energy

A

The minimum amount of energy required for a reaction to occur

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2
Q

An ENDothermic reaction

A

A reaction that takes energy from the surroundings,making the temp of surroundings decrease

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3
Q

An ENDothermic reaction (in terms of bonds)

A

The energy required to break existing bonds>energy released from making new bonds

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4
Q

An EXothermic reaction

A

A reaction that transfers energy to the surrounding ,making the temperature of surroundings increase

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5
Q

An EXothermic reaction(in terms of bonds)

A

The energy released from forming new bonds >than the energy required to break existing bonds

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6
Q

collision theory

A

Reaction can only take place between particles having the sufficient/activation energy

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7
Q

what is a catalyst

A

A substance that speeds up the rate of reaction without being used up

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8
Q

How does a catalyst work?

A

By providing an alternative reaction pathway with a lower activation energy

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9
Q

What are the two types of catalysts

A

Heterogenous catalyst-the catalyst is a different state to the reaction it is added to.

Homogenous catayst-the catalyst is the same state to the reaction it is added to.

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10
Q

What are the conditions that are neccassaary for a reaction to occur?

A

-Particles must have the correct oreintation
-Collisions must occur
-Particles must have sufficent/activation energy

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11
Q

what are factors that affect the rate of reaction?

A

-Temperature
-Surface Area
-Catalyst
-Concentration
-Pressure

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12
Q

What is the rate of reaction?

A

The measure of the amount of product formed/Time

OR

The amount of reactants used/Time

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13
Q

How does increasing temp affect the rate of reaction

A

-Particles have more kinetic energy so will move faster
-collide more often as a result =More frequent successful collisions
-A larger proportion of particles will have at least the activation energy

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14
Q

Describe how the temp change would be represented on a boltz-mann distributor

A

lower peak
more to the right
a significantly higher activation energy

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15
Q

How does increasing surface area increase the rate of reaction.

A

More particles are exposed to the other reactants
so more space for the atoms to interact =more frequent successful collisions.

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16
Q

Describe how the SA change would be represented on a boltz-mann distributor

17
Q

How does increasing the conc affect the rate of reaction

A

-Particles get closer together =so collide more often
-this leads to a higher rate of successful collisions

18
Q

How does the conc increase display on the boltz-mann distibution

A

It can’t
But it can be represented with a volume-time graph

19
Q

How does increasing the pressure affect the rate of reaction

A

Particles get closer together =so collide more often
-This leads to a higher rate of successful collisions

20
Q

How does the pressure increase display on the boltz-mann distibution

A

It can’t

but it can be represented with a cvolume/time graph .

21
Q

How does adding a catayst increase the rate of reaction

A

It speeds up the rate of reaction by providing an alternative reaction pathway that has a lower activation energy

22
Q

How does adding a catalyst change the representation on the boltzmann distibution

A

The position of the activation energy shifts to the left

23
Q

Why does the curve start at the origin

A

There are no molecules with no energy

24
Q

How do you find the rate from a curve

A

Draw a tangent ( change in y /change in x)

25
At a fixed temp does their average kinetic energy increase , decrease or stay the same
Stays the same /constant
26
The number of molecules being increased at a constant temperature How does this affect the: -The value of most probable energy -The number of molecules with the most probable energy -The area under the molecular distribution curve -The number of molecules with energy greater than the activation energy
The value of most probable energy= The number of molecules with the most probable energy =increase The area under the molecular distribution curve=increase The number of molecules with energy greater than the activation energy = increas ERRRORRRR
27
How does the following reasons affect the curve when the temperature is decreased without changing the number of molecules: -The value of most probable energy -The number of molecules with the most probable energy -The area under the molecular distribution curve -The number of molecules with energy greater than the activation energy
The value of most probable energy=increases The number of molecules with the most probable energy =increases The area under the molecular distribution curve=stays the same The number of molecules with energy greater than the activation energy = decrease