Last minute Flashcards

(18 cards)

1
Q

H2O2, CH3CO2H

A

Adds DB O to Sulfur

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2
Q

NaBH4

A

Weak reducing agent

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3
Q
  1. LAH
  2. H3O+
A

Strong reducing agent

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4
Q

HIO4, H2O

A

Cleaves diols if adjacent to each other

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5
Q

XS HBr

A

Changes ether to OH + EtBr

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6
Q

SAE + DET

A

Wedge

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7
Q

MeOH, H+

A

Cleaves epoxide, cis OH across DB

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8
Q
  1. NaOMe, DMSO
  2. H2O
A

Cleaves epoxide, OH and OMe (one wedge)

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9
Q

Mercapto

A

Prefix to use for thiol

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10
Q

LAH can take

A

esters off

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11
Q

ADD BOTH PRODUCTS in rXNS

A
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12
Q

ANY Cl-, COOH< ESTER, Grignard adds to the carbon, not substituting

A
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13
Q
  1. NaSH, DMSO
A

Sub and inversion

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14
Q

+ DET

A

Wedge

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15
Q
  • DET
A

Dash

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16
Q

Acid grabs ____ sub

17
Q

Base grabs ____ sub

18
Q

How to make ethers