Decomposition steps:
Role of ecosystem engineers?
Humus:
How does humus bond to metal ion?
Through chelation; humus is the ligand. Trivalent cations are more stable than divalent cations (stronger electrostatic bonds and chelate ring, and due to CFS)
Importance of chelation?
Improves soil formation, removes heavy metals, and prevents unwanted reactions involving essential nutrients. Chelated minerals are also more rapidly absorbed
What is a sesquioxide?
3 O and 2 metal atoms (3:2) e.g. Al2O3
- 50-90% organic matter bound to clay or sesquioxide
Extra bonds -> less decomposition
Phenolic
one or more OH bonded to an aromatic ring
- Most resistant substances of OM
- Form chains
- Can only be broken down by phenol oxydase
How do phenolics reduce decomposition?
Reduce decomposition of other organic molecules by interfering with enzymes.
Immobilisation
when mineralised components are taken up by micro-organisms for production of biomass
Strong competition between micro-organisms and roots for nutrients (from mineralisation) - microbes win
Can C from dissimilation be used for assimilation?
No because it is converted to co2 which disappears from the system