module 7 Flashcards by Michael Sokol

Q

R stereoisomer direction

A

clockwise

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Q

S stereoisomer direction

A

Counterclockwise

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Q

A

Isopropyl

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Q

A

t-butyl

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Q

A

sec-butyl

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Q

A

isobutyl

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Q

Z – stereoisomer

A

If the priority groups are on the same side

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Q

E – stereoisomer

A

If the priority groups are on opposite sides

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Q

Enantiomers

A

May have one or more stereocenters
All stereocenters must be switched between two structures
Have all the same physical properties except optical rotation

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Q

Diastereomers

A

Must have a minimum of two stereocenters
Must have at least one stereocenter remain the same
Completely different physical properties

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Q

Both enantiomers and diastereomers can affect _______ of a compound

A

biological impact

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Q

Suffix for alkanes

A

-ane

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Q

Suffix for alkenes

A

-ene

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Q

Suffix for alkynes

A

-yne

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Q

Substituent suffix for alkanes

A

-yl

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Q

Substituent suffix for alkenes

A

-enyl

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Q

Substituent suffix for alkynes

A

-ynyl

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Q

A

anisole

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Q

A

aniline

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Q

A

phenol

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Q

A

styrene

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Q

A

toluene

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Q

A

cumene

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Q

1-3

A

meta

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1-4

para

1-2

ortho

steroid

quinine

morphine

benzomorphan

phenylpiperidines

Barbituate

benzodiazepine

anesthetics

penicillin

What is the difference between a benzene and a heterocycle?

Benzene - aromatic Heterocycle - not aromatic

benzene

pyrrole

furan

thiophene

indole

catechol

pyrimidine

pyridine

imidazole

Fullerene aka "Bucky Ball"

naphthalene

anthracene

phenanthrene

pyrene

4-isopropylphenol (p-isopropylphenol)

3-methoxyaniline (m-methoxyaniline)

2-bromotoluene (o-bromotoluene)

3-methylstyrene (m-methylstyrene)

morpholine

piperazine

piperidine

tetrahydropyran

tetrahydrofuran

pyrrolidine