Free elements (uncombined state)
Have an oxidation number of zero.
NOTE: Free elements do NOT include ions.
In monoatomic ions…
The oxidation number is equal to the charge on the ion.
Oxygen
Oxygen usually has an oxidation number of -2. In H2O2 and O22, it is -1.
Hydrogen
Hydrogen has an oxidation number of +1, except when it is bonded to metals in binary compounds. In such cases, it’s oxidation number is -1.
Alkali metals
+1
Alkaline earth metals
+2
Fluorine
-1
In molecules or ions
The sum of the oxidation numbers of all the atoms in the molecule or ion is equal to the charge on the molecule of ion.
Do oxidation numbers have to be integers?
No, they can be fractions.