paper two Flashcards

(89 cards)

1
Q

what is metallic bonding?

A

the strong electrostatic attraction between positive metal ions and delocalised electrons

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2
Q

can metals conduct electricity?

A

yes

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3
Q

why can metals conduct electricity?

A

they contain delocalised electrons which are free to move

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4
Q

are metals malleable?

A

yes

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5
Q

why are metals malleable?

A

rows of metal ions can slide over each other easily

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6
Q

are metals strong?

A

yes

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7
Q

why are metals strong?

A

strong electrostatic attraction between positive metal ions and delocalised electrons

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8
Q

do metals have high or low melting points?

A

high

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9
Q

why do metals have high melting points?

A

the strong electrostatic attraction between positive metal ions and delocalised electrons requires lots of energy to overcome

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10
Q

what are alloys?

A

a mixture of a metal and one or more elements, usually other metals or carbon

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11
Q

why are alloys harder than pure metals?

A

in an alloy, the elements have slightly differently sized elements, which breaks up the normal lattice arrangement and prevents the layers sliding over each other

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12
Q

what are the uses of aluminium?

A
  • it is used for cables, some cars (because it’s light), planes, pots, and pans
  • it is useful because of it’s lack of corrosion, it’s low density, it’s strength when alloyed, and it is a good conductor of heat and electricity
  • it doesn’t corrode because it forms aluminium oxide on the surface
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13
Q

what is mild steel made up of?

A

iron and up to 0.25% carbon

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14
Q

what are the uses of mild steel?

A
  • nails, car bodies, ships, and bridges
  • mild carbon is strong, hard, malleable, and ductile
  • it rusts when exposed to oxygen and water
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15
Q

what is high-carbon steel made up of?

A

iron, 0.6-1.2% carbon, and small amounts of manganese

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16
Q

what are the uses of high-carbon steel

A
  • it is used for cutting tools and masonry nails
  • it is harder and more than resistant than mild steel, but also more brittle
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17
Q

what is stainless steel made up of?

A

iron, chromium, and usually nickel

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18
Q

what are the uses of stainless steel?

A
  • it is used in kitchen sinks, sauce pans, knives and forks, and gardening tools
  • it is also used in brewing, dairy, and chemical industries
  • it is resistant to corrosion
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19
Q

what are the uses of copper?

A
  • it is used in electrical wires, pots and pans, surfaces in hospitals, and water pipes
  • it is a good conductor of heat and electricity, it is unreactive, malleable, and has antimicrobial properties
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20
Q

what method is used to prepare a pure, dry sample of a soluble salt starting from an acid and an alkali?

A

use the titration method:
- do the titration
- use the titration values to measure out the right amount of acid and solid with no indicator!! bc it prevents the formation of crystals
- transfer to evaporating basin + heat
- allow solution to cool
- pick out crystals
- wash with distilled water
- pat dry with filter paper

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21
Q

what method is used to prepare a pure, dry sample of an insoluble salt starting from two soluble reactants?

A

the precipitation method:
- mix the two solutions together in a beaker
- stir with a rod
- filter with a filter paper + funnel
- wash with distilled water
- leave to dry in a warm oven

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22
Q

what colour is the precipitate formed when making a sample of lead (ii) sulphate using the precipitation method?

A

white precipitate

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23
Q

why does the reactivity of the metals in group 1 increase as you go down the group?

A
  • they all need to lose one electron
  • number of electron shells increases going down the group
  • outer electron gets further away from nucleus
  • attraction between nucleus and electron decrease
  • therefore it is easier to remove
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24
Q

why does the reactivity of the atoms in group 7 decrease as you go down the group?

A
  • all need to gain one electron
  • number of shells increases as you go down the group
  • so incoming electron is further away
  • so weaker attraction between incoming electron and nucleus
  • so harder to gain the electron
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25
what is the molar volume of a gas at room temp? in cm3 and dm3
24dm3 24,000cm3
26
what are the three equations with moles?
mass = mr x moles moles = conc x vol moles = vol/24 vol is always in dm
27
how do you do an acid-alkali titration?
- use a volumetric pipette to place 25cm cubed of the alkali into the conical flask - add a few drops of methyl orange or phenolphthalein - fill a burette with the acid and clamp it above the conical flask - measure initial vol with burette - add the acid into the flask drop by drop while swirling the flask - close burette tap as soon as the colour changes - measure final volume - calculate titre (final vol-initial vol) - repeat to get concordant titres
28
what does concordant mean?
within 0.2cm3
29
are the products above or below the reactants in an energy level diagram for endothermic reactions?
above
30
are the products above or below the reactants in an energy level diagram for exothermic reactions?
below
31
what does a positive ΔH value mean?
energy has been taken in
32
what does a negative ΔH value mean?
energy has been released
33
do exothermic reactions have a positive or negative ΔH value?
negative
34
is bond-breaking endothermic or exothermic?
endothermic - energy is taken in
35
is bond-making exothermic or endothermic?
exothermic - energy is released
36
how many arrows does the activation energy have on a reaction profile diagram?
ONE - pointing up i think
37
what is the functional group of acohols?
-OH
38
how can ethanol be oxidised?
- combustion - microbial oxidation - chemical oxidation
39
how can ethanol be manufactured?
- hydration of ethene - fermentation of glucose
40
what are the conditions needed for the hydration of ethene?
- 300 degrees - 65 atm pressure - phosphoric acid catalyst
41
what are the advantages of the hydration of ethene?
- one product (pure) - continuous process
42
what are the disadvantages of the hydration of ethene?
- requires a lot of energy - non-renewable raw material
43
what is the equation for the hydration of ethene?
C2H4 + H2O --> CH3CH2OH
44
what are the conditions for the fermentation of glucose?
- yeast - 30 degrees - anaerobic
45
what are the advantages of the fermentation of glucose?
- renewable raw material - less energy required
46
what are the disadvantages of the fermentation of glucose?
- impure ethanol - batch process
47
what catalyst is required for the hydration of ethene?
phosphoric acid
48
what flame colour is the combustion of ethene?
blue
49
what is the equation of complete combustion of ethanol?
ethanol + 3oxygen --> 2carbon dioxide +3water
50
what is the equation for microbial oxidation of ethanol?
ethanol + 2[O] --> ethanoic acid + water
51
what is the equation for the chemical oxidation of ethanol?
ethanol + 2[O] --> ethanoic acid + water
52
what is the oxidising agent in the chemical oxidation of ethanol?
potassium dichromate (VI)
53
what does the chemical oxidisation of ethanol require (other than the oxidising agent)?
- dilute sulphuric acid - water bath
54
what is the colour change in the chemical oxidation of ethanol?
orange --> green
55
what is the functional group of carboxylic acids?
COOH
56
what happens when a carboxylic acid reacts with a metal?
same as normal acid; forms a metal __oate + hydrogen
57
what happens when a carboxylic acid reacts with a metal carbonate?
same as a normal acid; forms a metal __oate + carbon dioxide + water
58
what is vinegar?
an aqueous solution containing ethanoic acid
59
what is the functional group of esters?
COO
60
how are esters formed?
alcohol + carboxylic acid (+ acid catalyst - eg sulphuric acid)
61
what is the ester produced when ethanol and ethanoic acid react in the presence of an acid catalyst?
ethyl ethanoate
62
how do you prepare an ester?
- mix carboxylic acid and alcohol together - add a few drops of concentrated sulphuric acid (catalyst) - warm gently
63
why don't covalent compounds conduct electricity?
there are no charged particles free to move
64
what is needed to make a polyester?
a dicarboxylic acid and a diol
65
what is the type of polymerisation used to form polyesters?
condensation polymerisation
66
what are the products of condensation polymerisation?
a polyester and water
67
how is an addition polyester formed?
by joining together lots of monomers
68
how reactive are polyesters?
they are inert because of their c-c bonds
69
why do ionic compounds only conduct electricity when molten or in a solution?
in a solid there are no ions free to move
70
what is an anion?
a negative ion
71
what is a cation?
a positive ion
72
what are electrodes made of?
graphite
73
why are electrodes made of graphite?
- can conduct - high melting point - low reactivity
74
what are positive electrodes called?
anodes - they attract anions
75
what are negative electrodes called?
cathodes - attract cations
76
why is a bulb placed in the circuit during electrolysis?
to show current is flowing
77
what is the rule at the anode for solution electrolysis?
- halogen is first priority - then oxygen if no halogen
78
what is the rule at the cathode during solution electrolysis?
takes metal or hydrogen, whichever is least reactive
79
what is the half equation at the anode during solution electrolysis when oxygen is attracted to it?
4OH- ---> O2 + 2H2O + 4e-
80
what are the characteristics of a reaction at dynamic equilibrium?
- forwards and reverse reactions occur at the same rate - concentrations of reactants and products remain constant
81
what will happen when a change in conditions is introduced to a system at equilibrium?
the position of equilibriums shifts to try and counter the change
82
what happens when you increase the amount of reactant in a system in equilibrium?
equilibrium position moves towards the product
83
what happens when you reduce the reactant in a system at equilibrium?
equilibrium point moves towards the reactants
84
what happens when you increase the pressure in a system at equilibrium?
the equilibrium point shifts to the side with less moles of gas
85
what happens when you decrease the pressure in a system at equilibrium?
the equilibrium point shifts to the side with more moles of gas
86
what happens when you increase the temperature in a system at equilibrium?
equilibrium shifts to the endothermic reaction
87
what happens when you decrease the temperature in a system at equilibrium?
promotes the exothermic reaction
88
do catalysts affect the point of equilibrium?
no
89
why don't catalysts affect the point of equilibrium?
because it speeds up both the forwards and the backwards reaction equally