quantum physics Flashcards

(31 cards)

1
Q

define photon

A

discrete quantum of electromagnetic energy

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2
Q

nature of electromagnetic radiation

A
  1. behave like wave:
    - diffraction
    -refraction
  2. behave like particle
    - photoelectric effect
    - atomic line spectra
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3
Q

equation energy of photon (Einstein’s relation)

A

E(eV) = h * f = (h * c)/ λ
E=energy(J)
h=Planck’s constant(Js)
f=frequency(Hz)

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4
Q

what is photoelectric effect

A

an interaction btw a photon and a electron in a metal, in which the electron is removed from the surface of a metal

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5
Q

equation momentum of photon in terms of E

A

P = E/ c
E=energy of photon
c=speed of light

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6
Q

what is electronvolt (eV)

A

The energy gained by an electron travelling through a potential difference of one volt

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7
Q

1 eV to joule

A

1 eV = 1.6 * 10^-19 J (elementary charge of electron)

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8
Q

kinetic energy of electron accelerated by potential difference from rest

A

eV = 1/2 * m * v^2
note: this does NOT apply when v approaches c (3*10^8)

v = √(2 * eV / m)

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9
Q

what is threshold frequency

A

the minimum frequency of an incident electromagnetic radiation required to remove a photoelectron form the surface of a metal

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10
Q

what is threshold wavelength

A

the longest wavelength of an incident electromagnetic radiation required to remove a phoelectron from the surface of a metal

note: related to threshold frequency by c = f * λ

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11
Q

define work function (threshold energy) Φ

A

the minimum energy required to release a photoelectron from the surface of a material

note: electron will be only emitted when absorbed a photon has energy more than Φ

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12
Q

how does work function varies with metals

A
  1. more tightly packed electron => more work function
  2. metallic bonding stronger
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13
Q

what is stopping potential

A

potential difference required to stop photoelectrons emission from occurring

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14
Q

equation max Ek of phototelectron in terms of stopping voltage

A

Ek max = e * Vs
e=elementary charge of electron
Vs=stopping voltage

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14
Q

how is max Ek determined

A
  1. set up circuit with emitter plate, collector plate and variable emf
  2. as photon reaches emitter plate, photoelectron is emitted and collected by the collector plate, creating a current, thus pd
  3. the variable emf is set to be opposite to the photo cell, only electron possess more Ek than the emf can reach the collector plate
  4. as the opposition emf increases, eventually no electron can reach the collector plate, thus max Ek is determined by this stopping potential

note: V = W/Q = E/Q = Ek/e

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15
Q

factors that effect the maximum Ek of photon

A
  1. frequency (or wavelength) of incident wave
  2. work function of the metal

which means that the stopping potential will be the same

16
Q

what does increasing intensity effect

A
  1. increases the number of photon incident to the metal surface (if frequency kept the same)
  2. increase the photoelectric current (the number of photoelectron emitted)
  3. increase the energy transferred per unit area in a given time
  4. will not effect Ek

note: intensity is power per unit area (rate of energy dissipated per unit area)

17
Q

what happens to photoelectric current when frequency increases but intensity remain the same

A
  1. f incr => E of each photon incre (E = hf)
  2. intensity constant => energy transferred per unit area in a given time is constant
  3. therefore, the number of photo per unit area decreases
  4. one electron absorb one photon => photoelectron emitted decre
18
Q

photoelectric equation

A

E = h*f = Φ + Ek = Φ + 1/2 * m * v^2(max)

E=energy of photon
Φ=work function(energy required for photoelectron to be emitted)
m=mass of photoelectron
vmax= max velocity of photoelectron
Ek=kinetic energy gained by photoelectron

19
Q

relation Ek against f

A

Ek = h*f - Φ

20
Q

what is photoelectric current

A
  1. number of photoelectron emitted per unit time
  2. value of photoelectric current = number of electron emitted * charge of one electron
21
Q

define de Broglie wavelength

A

wavelength associated with a moving particle

22
Q

equation of de Broglie wavelength

A

λ = h / p. = h / √(2 * m * Ek)

λ=de Broglie wavelength
h=plank’s constant
p=momentum of particle

m=mass of particle
Ek=kinetic energy of particle

23
Q

equation for kinetic energy in terms of moementum

A

Ek = p^2 / 2m
p=momentum
m=mass

24
what is electron energy level
discrete electron energy level in isolated atoms electrons are usually at ground state (lowest energy level)
25
what happens when electron moves btw energy level
1. when electron absorbs enough energy to move up energy level, it is excited 2. when gains enough energy to be removed from the atom, it is ionised 3. when drops energy level, it releases energy in form of photon
26
how to find the ionisation energy an electron hydrogen atom
the difference btw Einfinity (which is 0) and E1, therefore same as ground level energy
27
how to find threshold frequency
Φ = h*f
28
what is line spectra
1. when excited atoms emit light of specific wavelength, which creates a unique pattern of coloured lines 2. there are discrete energy levels => discrete wavelength will be emitted 3. useful to determine the material 3. Emission Spectra: when excited electron move from higher to lower energy level, light of specific wavelength is emitted 3. absorption Spectra: when shine a light through a gas of substance, light of specific wavelength will be absorbed to excite the electrons, so certain wavelength will be missing
29
why only certain wavelength is absorbed
1. photon is indivisible 2. only those possess energy exactly the same as the difference btw energy levels will be absorbed to excite electrons (other ones will be ignored) 3. this only applies to photon
30
calculate discrete energy changes
hf = E2 - E1 note: dont forget the negative sign