r2 Flashcards

(37 cards)

1
Q

What are the full steps for gas stoichiometry problems?

A
  1. Balance equation
  2. Convert given to moles (PV=nRT or molar ratio)
  3. Apply mole ratio
  4. Convert to final unit
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2
Q

Ideal Gas Law equation and variables

A

PV = nRT
P = pressure (Pa or atm)
V = volume (m³ or dm³)
n = moles
R = 8.31 J/mol·K or 0.0821 L·atm/mol·K
T = Kelvin

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3
Q

metal carbonate + acid yields to?

A

salt + water + carbon dioxide

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4
Q

metal bicarbonate + acid yields to?

A

salt + water + carbon dioxide

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5
Q

Full collision theory requirements

A
  1. Collisions must occur
  2. Correct orientation
  3. Kinetic energy ≥ activation energy
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6
Q

Effect of concentration on collision frequency

A

More particles per volume → more collisions per second

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6
Q

Why does increasing temperature increase rate (HL explanation)?

A

Maxwell–Boltzmann distribution shifts right

Larger fraction of molecules exceed Ea

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7
Q

simple endothermic graph

A

reactants lower than products

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8
Q

simple exothermic graph

A

reactants higher than products

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8
Q

Maxwell-Boltsmann energy curve x-axis

A

kinetic energy, E

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9
Q

Maxwell-Boltsmann energy curve y-axis

A

number of particles with kinetic energy, E

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10
Q

What does the left of the activation energy line on the Maxwell-Boltsmann energy curve represent

A

The proportion of particles that do not have enough energy to react.

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11
Q

What does the right of the activation energy line on the Maxwell-Boltsmann energy curve represent

A

The proportion of particles that do have enough energy to react.

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12
Q

0 order

A

changing concentration of the reactant has no effect on the rate of the reaction

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13
Q

1st order

A

changing concentration of the reactant change the rate of the reaction by the same factor

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14
Q

2nd order

A

changing concentration of the reactant change the rate of the reaction by the same factor^2

15
Q

what is the Arrhenius equation used to determine

A

activation energy

16
Q

Arrhenius equation

17
Q

Arrhenius plot equation

A

ln (k) = ln (A) - Ea/R x 1/Tk

18
Q

k «_space;1

A

reaction hardly proceeds

19
Q

k < 1

A

equilibriam torwards the products

20
Q

k = 1

A

significant amounts of both procuta and reactant at quillibiriam.

21
Q

k > 1

A

equilibriam torwards the reactants

22
Q

k»_space; 1

A

reaction goes almost to completion

23
Q = K
no net reaction occurs
24
Q < K
reaction proceeds to the right, products are favoured
25
Q > K
reaction proceeds to the left, reactants are favoured
26
Delta G -
lnk + k > 1 forward reaction products spontaneous
27
Delta G +
lnk 1 k < 1 reverse reaction reactants
28
Arrhenius slope
Ea/r
29
Change in equilibrium: Increase in products
right
30
Change in equilibrium: Increase in reactants
left
31
Change in equilibrium: Increase pressure
favor lesser moles of gas
31
Change in equilibrium: Decrease pressure
favor more moles of gas
32
Change in equilibrium: Increase temperature
favors reverse reaction (endothermic)
33
Change in equilibrium: Decrease temperature
favors forward reaction (exothermic)
34
What is the only way to change the K value
change temperature