Rainwater is naturally acidic -
Unpolluted rainwater in equilibrium with CO2 has a pH of 5.65.
pH of pure water -
7.0
Carbon dioxide reacts with water to produce
Hydrogen H+ ions and carbonate HCO3- ions.
Hydrogen carbonate ions can dissociate further to
Produce carbonate H+ ions and CO3 2- ions.
pH can be significantly higher than 5.6 in areas where
Calcareous dust is blown into the atmosphere.
Naturally occurring gaseous sulfur and nitrogen oxides from
Biological activity and volcanoes can lower the pH of rainwater.