RXNS Flashcards by Roxana Boff

Q

HYDROHALOGENATION

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Q

HYRDROHALOGENATION (WITH REARRANGMEMENT)

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Q

HALOGENATION

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Q

HYDROBROMINATION WITH PEROXIDE

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Q

HYDRATION

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Q

HYDRATION WITH REARRANGEMENT

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Q

BROMINATION IN H20

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Q

OXYMERCURATION - DEMERCURATION

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Q

HYDROBORATION-OXIDATION

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Q

SYN DYHYDROXYLATION

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Q

SYN DYHYDROXYLATION

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Q

ANTI-DIHYDROXYLATION

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Q

ADDITION OF AN ALCOHOL

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Q

BROMINATION IN ALCOHOL

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Q

ALKOXYMERCURATION- DEMERCURATION

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Q

EPOXIDATION

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Q

CATALYTIC HYDROGENATION

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Q

OZONOLYSIS (REDUCING CONDITIONS)

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Q

OZONOLYSIS (OXIDIZING CONDITIONS/ OXIDATIVE CLEAVAGE)

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Q

CATALYTIC HYDROGENATION (CATALYTIC REDUCTION)

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Q

REDUCTION TO CIS-ALKENE

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Q

REDUCTION TO TRANS-ALKENE

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Q

HYDROHALOGENATION WITH HBR (TERMINAL ALKYNE)

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Q

HYDROHALOGENATION WITH HBR ( INTERNAL ALYKYNE)

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HALOGENATION WITH BR2

HYDRATION OF AN INTERNAL ALKYNE

HYDRATION OF A TERMINAL ALKYNE ( MARKOVNIKOV)

HYDRATION OF A TERMINAL ALKYNE ( ANTI-MARKOVNIKOV)

SN2 ADDITION OF AN ACETYLIDE ION TO AN ALYKL HALIDE

SN2 ADDITION OF ACETYLIDE ION TO A KETONE

SN2 ADDITION OF AN ACETYLIDE ION TO AN EPOXIDE

OZONOLYSIS/OXIDATIVE CLEAVAGE OF AN INTERNAL ALKYNE

OZONOLYSIS/OXIDATIVE CLEAVAGE OF A TERMINAL ALKYNE

ALYKNE FORMATION FROM DOUBLE ELIMINATION OF A VICINAL DIHALIDE

FREE RADICAL HALOGENATION USING BROMINE (MORE SELECTIVE)

FREE RADICAL HALOGENATION USING CHLORIDE (LESS SELECTIVE)

ACYLIC/BENZYLIC BROMINATION

DIENE ADDITION TO AN DIENOPHILE (ALKENE)

DIENE ADDITION TO A DIENOPHILE (ALKYNE)

DIENE ADDITION TO A CIS DIENOPHILE

DIENOPHILE TO A TRANS DIENOPHILE

DIENE ADDITION TOA SUBSTITUTED DIENOPHILE

ADDITION OF A GRIGNARD REAGENT TO AN ALDEHYDE

ADDITION OF A GRIGNARD REAGENT TO AN KETONE

ADDITION OF A GRIGNARD REAGENT TO AN ESTER

ADDITION OF A GRIGNARD REAGENT TO AN ACYL CHLORIDE

ADDITION OF A GRIGNARD REAGENT TO CO2

ADDITION OF A GRIGNARD REAGENT TO AN EXPOXIDE ( ADDS TO THE LESS SUBS. SIDE)

ADDITION OF A GRIGNARD REAGENT TO A CARBOXYLIC ACID

ADDITION OF A GRIGNARD REAGENT TO AN AMIDE

ADDITION OF A GRIGNARD REAGENT TO A NITRILE

FRIEDEL CRAFTS ALKYLATION ( REARRANGEMENT POSSIBLE)

FRIEDEL CRAFTS ALKYLATION (NO REARRANGEMENT POSSIBLE)

BROMINATION

CHLORINATION

NITRATION

SULFONATION

FORMYLATION

EAS WITH AN ORTHO/PARA DIRECTING GROUP ON BENZENE

EAS META-DIRECTING GROUP ON BENZENE

FRIEDEL-CRAFTS ALKYLATION/ACYLATION WITH A META-DIRECTING GROUP OR AN AMINE ON BENZENE

SIDE CHAIN OXIDATION OF BENZENE TO FORM BENZOIC ACID

SIDE CHAIN OXIDATION OF BENZENE TO FORM BENZOIC ACID

WOLF-KISHNER REDUCTION

CLEMMENSEN REDUCTION

ACETYLATION OF ANALINE USING ACETIC ANHYDRIDE

DIAZONIUM SALT REACTIONS

DIAZONIUM SALT REACTIONS

REDUCTION OF AN ALDEHYDE TO A 1 ALCOHOL

REDUCTION OF A KETONE TO A 2 ALCOHOL

REDUCtION OF A CARBOXYLIC acid to a 1 alcohol

REDUCTION OF AN ESTER TO AN 1 ALCOHOL

REDUCTION OF AN ESTER TO AN ALDEHYDE

REDUCTION OF AN ACYL CHLORIDE TO A 1 ALCOHOL

REDUCTION OF AN ACYL CHLORIDE TO A 1 ALCOHOL

REDUCTION OF AN AMIDE TO AN AMINE

REDUCTION OF AN ACYL CHLORIDE TO AN ALDEHYDE

HOFMANN REARRANGEMENT

REDUCTION OF A NITRILE TO AN AMINE

CONVERSION OF A 2/3 ALCOHOL TO AN ALKYL HALIDE VIA SN1

CONVERSION OF A 1/2 ALCOHOL TO AN ALKYL BROMIDE VIA SN2

CONVERSION OF A 1/2 ALCOHOL TO AN ALKYL CHLORIDE VIA SN2

CONVERSION OF AN ALCOHOL TO A TOSYLATE ESTER (OTS)

ACID CATALYZED DEHYDRATION OF AN ALCOHOL

CHROMIC ACID OXIDATION OF A 1 ALCOHOL TO A CARBOXYLIC ACID

CHROMIC ACID OXIDATION OF A 2 ALCOHOL TO A KETONE

Chromic Acid Oxidation of an Aldehyde to a Carboxylic Acid

PCC or DMP Oxidation of a 1 Alcohol to an Aldehyde

PCC or DMP Oxidation of a 2 Alcohol to a Ketone

Oxidative Cleavage of a 1,2 Diol

Swern Oxidation

Williamson Ether Synthesis via SN2

Acid-catalyzed Cleavage of Ethers when one side is 2 ̊/3 ̊ (Nucleophile attacks more substituted side via SN1)

ACID CATALYZED CLEAVAGE OF ETHERS WHEN NEITHER SIDE IS 2/3 (NUCLEOPHILE ATTACKS LESS SUB. SIDE VIA SN2)

ACID CATALYZED RING OPENING OF EPOXIDES (NUCLEOPHILE ATTACKS MORE SUB. SIDE)

BASE CATALYZED RING OPENING OF EPOXIDES (NUCLEOPHIOLE ATTACKS LESS SUB. SIDE)

NUCLEOPHILIC ADDITION TO AN ALDEHYDE OR KETONE

ADDITION OF WATER TO AN ALDEHYDE OR KETONE FORMING A HYDRATE

BASE CATALYZED ADDITION OF AN ALCOHOL TO AN ALDEHYDE OR KETONE FORMING A HEMI-ACETAL/HEMI-KETAL

ACID CATALYZED ADDITION OF AN ALCOHOL TO AN ALDEHYDE OR KETONE FORMING A ACTETAL/KETAL (PROTECTING GROUP, REVERSED BY H30)

ACID CATALYZED ADDITION OF ETHYLENE GLYCOL TO AN ALDEHYDE OR KETONE FORMING ACETAL/KETAL (PROTECTING GROUP, REVERSED BY H30)

ADDITION OF A 1 AMINE TO AN ALDEHYDE OR KETONE FORMING AN IMINE ( REVERSED BY H30)

Addition of a 2 ̊ Amine to an Aldehyde or Ketone forming an Enamine (Reversed by H3O +)

ADDITION OF A WITTIG REAGENT TO AN ALDEHYDE/KETONE

Michael Addition to an α, β Unsaturated Ketone

Michael Addition to an α, β Unsaturated Ketone with a Gilman Reagent (Organocuprates)

Acid-catalyzed Hydrolysis of a Nitrile

SN2 formation of Nitriles using Cyanide and Alkyl Halides

Cyanohydrin Formation using Aldehydes/Ketones and Cyanide

Carboxylic Acid Derivative Reactions

Self Aldol Condensation and Enone Formation

Mixed Aldol Condensation and Enone Formation

Self Claisen Condensation

Mixed Claisen Condensation

Dieckmann Cyclization (Intramolecular Claisen Condensation)

Acetoacetic Ester Synthesis

Malonic Ester Synthesis

Alpha Halogenation In Basic Conditions

Alpha Halogenation in Acidic Conditions

Haloform Reaction