Structure 3.1 Flashcards

(47 cards)

1
Q

What are groups

A

Vertical column

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2
Q

What are periods

A

Horizontal row

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3
Q

Group 1 name

A

Alkali metals

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4
Q

Group 2 name

A

Alkali earth metals

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5
Q

Group 7/17 name

A

Halogen

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6
Q

Group 8/18 name

A

Noble gases

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7
Q

What is electron shielding?

A

Electron shielding occurs when inner shielding electrons shield the outer valence electrons the full attraction of the nucleus.

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8
Q

State the variance in electron shielding according to the periodic table

A
  • Constant across period
  • Increasing down a group
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9
Q

What is effective nuclear charge?

A
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10
Q

State the variance in effective nuclear charge according to the periodic table

A
  • Increases across period
  • Constant down group
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11
Q

Comment on the trend in atomic radii across a period

A

Decreases due to higher positive charge and same amount of shielding.

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12
Q

Comment on the trend in atomic radii down a group

A

Increases due to more energy levels.

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13
Q

Comment on the general rule for ionic radii

A

Ionic radius is smaller for positive ions and larger for negative ions

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14
Q

Define first ionisation energy

A

Energy required to remove one mole of electrons from one mole of gaseous atoms to make a mole of +1 gaseous atoms

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15
Q

Trend in ionisation energy down a group

A

Decrease due to less energy needed

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16
Q

Trend in ionisation energy across a period

A

General increase due to more energy needed

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17
Q

What is first electron affinity

A

The energy released when adding one mole of electrons to one mole of gaseous atoms

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18
Q

Comment on the endothermic/exothermic of first electron affinity vs second

A

First electron affinity is negative so exothermic whereas second is positive so endothermic

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19
Q

Why are second electron affinity values negative

A

Electron repulsion

20
Q

Define Electronegativity

A

The measure of an attractiveness of an atom

21
Q

Where are group 1 elements stored

A

Oil to prevent reaction with oxygen

22
Q

What happens when alkaline metals, group 1, react with water

A

React vigorously to produce an alkaline solution and hydrogen gas

23
Q

What does group 1 + 17 give

24
Q

Comment on the reactivity of group 17 elements

A

Less reactive down the group

25
Comment on the pH of the group 3 oxides
26
Acids of sulfur
27
Acids of nitrogen
28
Summarise sources of acid rain
29
Comment on ocean acidification
There is an equilibrium between ocean CO2 and air CO2
30
Reaction between CO2 and H2O in ocean
Forms carbonic acid
31
What happens to carbonic acid in the ocean
Partially dissociates to form H+ which decreases ocean pH levels
32
Define oxidation state
Hypothetical charge an atom would have if the bonds were ionic
33
Oxidation state of elements
0
34
Sum of oxidation states in a compound
0
35
Oxidation state of H
+1
36
Oxidation state of O
-2 (Unless H2O2 => O = -1) or (OF2 => O = +2)
37
Oxidation state of F
-1
38
Oxidation state of Cl
-1 unless paired with O or F in which case they take precedence
39
Give the two reasons for the inconsistencies in ionisation energy trend
- P orbitals are further from nucleus than S - Doubly occupied orbitals have repulsion
40
Summarise the properties of transition elements
41
Explain paramagnetic
Paragegnetism increases with number of unpaired electrons
42
What are complex ions made up of
Ligands + central metal ion
43
What are coordinate compounds made of
Complex ions + counterions
44
What type of bonding between ligands and central metal ion?
Coordinate covalent
45
State crystal field theory
The properties of complex ions are caused by the splitting of the d orbitals into two sets of energy
46
State the relation between absorbed wavelength and transmitted
Complementary on the colour wheel
47
Bullet point why complex ions show colour
- D orbitals in transition elements split into two sets of higher and lower - Energy gap corresponds to the wavelength of visible light - Electrons can transition between these levels