What is internal energy?
Sum of the potential and kinetic energies of a system
How can you increase the thermal energy of a system?
By heating it or doing work on it
Energy changes during a change of state?
Potential energy changes; kinetic energy stays constant
Equation for energy to change temperature?
Q = mcΔT
Equation for energy to change state?
Q = ml
Ideal gas equation?
pV = nRT
First law of thermodynamics?
ΔU = Q - W, Q = heat added, W = work done by system
Specific heat capacity?
Energy required to raise 1kg of a substance by 1K
Define Specific latent heat
Energy required to change the state per unit mass at constant temperature
Ideal gas definition?
Molecules don’t interact, considered perfect spheres
Internal energy of ideal gas?
Equal to the sum of kinetic energies of particles
Boyle’s law?
Pressure ∝ 1/volume at constant temperature
Effect of increasing volume at constant pressure?
Temperature increases
Effect of increasing temperature at constant volume?
Pressure increases due to higher kinetic energy and more frequent collisions
Absolute zero?
-273°C; minimum kinetic energy
Avogadro’s constant?
Number of particles in 1 mole of a substance
Elastic collisions assumption?
True; all particle collisions are elastic
Time assumption for ideal gas?
Collision time negligible compared to time between collisions
Other assumptions of ideal gas?
Particles move randomly, obey Newton’s laws, no intermolecular forces, particle volume negligible
Root mean square speed?
√(mean of the squares of particle speeds)
Brownian motion?
Random motion of small particles due to collisions with molecules, evidence for atoms