Thermal Physics Flashcards

(34 cards)

1
Q

Definition of internal energy of a substance

A

Sum of randomly distributed kinetic and potential energies of the molecules in a substance

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2
Q

Definition of the potential energy of a molecule

A

The energies that particles have due to the electrostatic attraction that exists with other particles (in a non-ideal gas)

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3
Q

Why is potential energy of a molecule always negative?

A

Energy must be supplied to break the atomic/molecular bonds

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4
Q

What is potential energy defined to be in a gas?

A

0

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5
Q

Why is potential energy 0 in a gas?

A

There are negligible electrostatic forces between the atoms

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6
Q

Describe potential energy in a liquid

A

Has a negative value due to the electrostatic forces that need energy to be broken.

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7
Q

Describe potential energy in a solid

A

The electrostatic forces between atoms are very large, giving the potential energy a large negative value

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8
Q

What is specific latent hear

A

The energy needed to change the state of 1kg of a substance

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9
Q

What is the triple point?

A

the specific temperature and pressure where all 3 phases of matter can exist in thermal equilibrium at the same time

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10
Q

What is the triple point for water?

A

0.01C & 0.6 kPa (less than 1% of normal atmospheric pressure

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11
Q

How to work out Kelvin?

A

C + 273.15

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12
Q

Give the main properties of solids, including the molecular form and intermolecular forces:
How are atoms packed?
What arrangement?
What structure?
What is between atoms?
What do atoms vibrate around?
Therefore having what?

A

Close together
Regular arrangement
Crystalline structure.
Strong electrostatic forces of attraction
A fixed spot
KE

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13
Q

Give the main properties of liquids, including the molecular form and intermolecular forces:
How many atoms?
Packed?
Arrangement? (2)
What don’t atoms have?
but they can..?
KE in relation to other states?

A

Many
Closely together
Not as regular as solids, can vary through time
Much space to move
Slide over each other, changing position.
More KE than atoms in a solid.

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14
Q

Give the main properties of gasses, including the molecular form and intermolecular forces:
Arrangement of molecules?
Space between atoms compared to solids & liquids?
More or less KE?
what are atoms free to do?
what are the electrostatic forces between atoms?

A

No arrangement
Larger
More KE
Move past each other
Negligable

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15
Q

What is the definition of temperature?

A

a measure of how hot or cold something is

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16
Q

In what state is electrostatic PE the highest?

17
Q

What number can the PE of a substance never be?

18
Q

What is absolute temperature?

A

temperature measured using the Kelvin scale where absolute 0 is 0 kelvin

19
Q

Define specific heat capacity

A

the amount of heat energy needed to raise the temperature of 1kg of a substance by 1 C / 1K

20
Q

What are the units for specific heat capacity?

A

Jkg^(-1)K^(-1)

21
Q

Equations that relates energy, mass, specific heat capacity, and change in temperature

22
Q

What is thermal equilibrium?

A

When two objects have 0 resultant energy transfer between them.

23
Q

When does thermal equilibrium occur?

A

only when the temperatures between two objects are equal

24
Q

In which direction does temperature transfer occur?

A

transfers from high to low

25
What is the relationship between changes in hot temperatures and changes in cold temperatures?
∆E hot - ∆E cold
26
Which equation can be used to show the relationship between changes of energies and temperatures?
mc(hot)∆T(hot-final) = mc(cold)∆T(final-cold)
27
In an investigation for the SHC of a liquid such as water, what equipment would be required?
thermometer, cotton wool (insulator), solid block, immerstion heater
28
In an investigation for the SHC of a liquid, which measurements need to be taken?
t = time the heater is on for, T = temperature at specific intervals, V = voltage, I = current, m = mass of block
29
In an investigation for the SHC of a liquid, how would you minimise the uncertainty?
use electrical equipment instead of a thermometer
30
use t, T, V, I, and m to find c
E = Pt = ItV E = mc∆T ItV = mc∆T c = ItV/m∆T
31
Which quantities remain the same as a substance undergoes a change of state?
KE and temperature
32
What are the units for pv/T?
Jmol^(-1)K^(-1)
33
Which type of energy is responsible for a change in temp of a material?
Kinetic
34
Which type of energy is responsible for a change of state in a material?
potential