Definition of internal energy of a substance
Sum of randomly distributed kinetic and potential energies of the molecules in a substance
Definition of the potential energy of a molecule
The energies that particles have due to the electrostatic attraction that exists with other particles (in a non-ideal gas)
Why is potential energy of a molecule always negative?
Energy must be supplied to break the atomic/molecular bonds
What is potential energy defined to be in a gas?
0
Why is potential energy 0 in a gas?
There are negligible electrostatic forces between the atoms
Describe potential energy in a liquid
Has a negative value due to the electrostatic forces that need energy to be broken.
Describe potential energy in a solid
The electrostatic forces between atoms are very large, giving the potential energy a large negative value
What is specific latent hear
The energy needed to change the state of 1kg of a substance
What is the triple point?
the specific temperature and pressure where all 3 phases of matter can exist in thermal equilibrium at the same time
What is the triple point for water?
0.01C & 0.6 kPa (less than 1% of normal atmospheric pressure
How to work out Kelvin?
C + 273.15
Give the main properties of solids, including the molecular form and intermolecular forces:
How are atoms packed?
What arrangement?
What structure?
What is between atoms?
What do atoms vibrate around?
Therefore having what?
Close together
Regular arrangement
Crystalline structure.
Strong electrostatic forces of attraction
A fixed spot
KE
Give the main properties of liquids, including the molecular form and intermolecular forces:
How many atoms?
Packed?
Arrangement? (2)
What don’t atoms have?
but they can..?
KE in relation to other states?
Many
Closely together
Not as regular as solids, can vary through time
Much space to move
Slide over each other, changing position.
More KE than atoms in a solid.
Give the main properties of gasses, including the molecular form and intermolecular forces:
Arrangement of molecules?
Space between atoms compared to solids & liquids?
More or less KE?
what are atoms free to do?
what are the electrostatic forces between atoms?
No arrangement
Larger
More KE
Move past each other
Negligable
What is the definition of temperature?
a measure of how hot or cold something is
In what state is electrostatic PE the highest?
gases
What number can the PE of a substance never be?
0
What is absolute temperature?
temperature measured using the Kelvin scale where absolute 0 is 0 kelvin
Define specific heat capacity
the amount of heat energy needed to raise the temperature of 1kg of a substance by 1 C / 1K
What are the units for specific heat capacity?
Jkg^(-1)K^(-1)
Equations that relates energy, mass, specific heat capacity, and change in temperature
E = mc∆c
What is thermal equilibrium?
When two objects have 0 resultant energy transfer between them.
When does thermal equilibrium occur?
only when the temperatures between two objects are equal
In which direction does temperature transfer occur?
transfers from high to low