Thermodynamics Flashcards

(13 cards)

1
Q

Enthalpy of formation

A

Enthalpy change when one mole of a substance is formed from its constituent elements with all the substances in their standard states.
Exo/endo

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2
Q

Enthalpy of combustion

A

Enthalpy change when one mole of s substance undergoes complete combustion in oxygen.
Exo

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3
Q

First Ionisation Enthalpy

A

The first ionisation energy is the Enthalpy change when one mole of gaseous atoms loses one electron per atom to produce gaseous 1+ ions.
Endo

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4
Q

Second Ionisation Enthalpy

A

The second ionisation energy is when one mole of gaseous 2+ ions is produced from one mole of 1+ ions.
Endo

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5
Q

First electron affinity

A

The first electron affinity is the Enthalpy change when one mole of gaseous atoms gains one electron per atom to produce gaseous 1- ions.
Exo

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6
Q

Second electron affinity

A

The second electron affinity is the Enthalpy change when one mole of gaseous 1- ions gains one electron per ion to produce gaseous 2- ions.
Endo

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7
Q

Enthalpy of atomisation

A

When one mole of gaseous atoms is produced from an element in its normal state.
Endo

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8
Q

Hydration Enthalpy

A

Enthalpy change when one mole of gaseous ions becomes hydrated (dissolved in water).
Exo

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9
Q

Enthalpy of solution

A

Enthalpy change when one mole of an ionic solid dissolves in an amount of water large enough so that the dissolved ions are well separated and do not interact with each other.
Exo/endo

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10
Q

Bond dissociation Enthalpy

A

Enthalpy change when one mole of covalent bonds is broken in the gaseous state.
Endo

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11
Q

Lattice Enthalpy of formation

A

Enthalpy change when one mole of a solid ionic compound is formed from its constituent ions in the gas phase.
Exo

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12
Q

Lattice Enthalpy of dissociation

A

Enthalpy chnage when one mole of a solid ionic compound is broken up into its constituent ions in the gas phase.
Endo

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13
Q

Perfect ionic model

A

Ions are perfect spheres with no covalent character

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