Pauli Exclusion Principle
2e- within same orbital must have opposite spins
Hounds Rule
Give each orbital 1e- before pairing (within same energy level)
Aufbow Principle
Fill lower energy orbitals first
Magnetic Quantum Number, Ml
Orientation of e- orbitals
Values: -l:+l
Spin Quantum Number Ms
Relates to the spin of e-
Values: +1/2 or -1/2
Principle Quantum Number, n
Relates to energy of e-
Values: integer
Secondary Quantum Number, L
Relates to the shape
Values: 0 to (n-1)
Ferromagnetic
Strong magnet
Less atoms = stronger magnetism
Paramagnetic
Weak magnet
Not noticed unless interacting with strong magnet
Hybridization
Atomic orbital -> molecular orbitals
- Shapes resemble combinations of atomic orbitals
- Make covalent bonds
Energy levels and their max e-
S^2, P^6, D^10, F^
How does a molecule hybridize?
Takes from s orbital
Fills p orbitals via hunds Rule
P orbitals extend and overlap tp make pi bonds
Sigma bonds
Overlap of SP orbital
Triple bond(?)
Bond Order
= (#bonding e-) - (#antibonding e-) / 2
AX2
SP hybridized
180
Linear
AX3
120
Trigonal Planar
SP2
AX4
SP3
109.5
Tetrahedral
AX5
sp3d
Trigonal bipyramidal
90
105
AX6
sp3d2
Octahedral
Determining its geometry
AX3E
SP3
Trigonal pyramidal
107
AX2E2
SP3
Bent
Lone pairs on geometry
Lone pairs take up less space and push away
VSEPR
Valence
Shell
Electron
Pair
Repulsion