unit 4 Flashcards

(47 cards)

1
Q

What is the base equilibrium constant?

A

Kb

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2
Q

What is the expression for Kb?

A

[HB+][OH-] / [B]

HB+ is the conjugate acid
B is the base

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3
Q

Kb is less than 1

A

Weak base

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4
Q

Kb is greater than 1

A

Strong base

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5
Q

Lower Kb means

A

Weaker base

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6
Q

Weak electrolyte

A

partially dissolves

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7
Q

Strong electrolyte

A

completely dissolves

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8
Q

If [H+] increases, then pH

A

decreases

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9
Q

If [H+] decreases, then pH

A

increases

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10
Q

What is the equation for pH?

A

pH= -log[H+]

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11
Q

What is the equation for pOH?

A

pOH= -log[OH-]

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12
Q

What is the equation for [H3O+]?

A

[H3O+] = 10^-pH

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13
Q

What is the equation for [OH-]?

A

[OH-] = 10^-pOH

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14
Q

When can you substitute H+ in the pH equation?

A

When you have a strong acid

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15
Q

What are the strong acids?

A

HCl
HBr
HI
HNO3
HClO3
HClO4
H2SO4

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16
Q

What are the weak acids?

A

HF
CH3COOH
CHOOH
H2SO3
H2CO3
H3PO4

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17
Q

What are the strong bases?

A

LiOH
NaOH
BaOH
Ca(OH)2
Sr(OH)2
Ba(OH)2

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18
Q

What are the weak bases?

A

NH3
F-
NO2-
C2H3O2-
CN-
HSO3
CH3NH2
C2H5NH2
C5H5N

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19
Q

If you have a strong acid, the conjugate base will be

20
Q

If you have a weak acid, the conjugate base will be

21
Q

What is the Arrhenius definition of acids and bases

A

Bases produce OH- ions in solutions
Acids produce H+ ions in solutions

22
Q

What is the Brønsted-Lowry definition of acids and bases?

A

Acids are H+ donors
Bases are H+ acceptors

23
Q

Where do we see conjugate bases/acids present?

A

Bronstead-Lowry acids and bases

24
Q

How do you identify which substance is the conjugate acid?

A

Which ever one has the hydrogen “added” to it

25
How do you identify which substance is the conjugate base?
Which ever one has the hydrogen going "bye bye"
26
Define amphoterism
When a substance (which must have hydrogen) can act as both an acid and a base
27
Autoionization
Water acting with itself
28
[H3O+] is greater than [OH-]
Acidic solution
29
[H3O+] is less than [OH-]
Basic solution
30
[H3O+] is equal to [OH-]
Neutral solution
31
pH < 7
Acidic
32
pH > 7
Basic
33
pH = 7
Neutral
34
pOH < 7
Basic
35
pOH > 7
Acidic
36
pOH = 7
Neutral
37
Kw expression
Kw = 1.0 x 10^-14M at 25 degrees celsius Kw = [H3O+][OH-]
38
When given a picture, how do you identify the strong acid versus weak acid?
A strong acid dissociates completes so it will have more single ions and less molecules A weak acid dissociates partially so it will have less ions and more molecules
39
pKA equation
pKa= -log(Ka)
40
Higher Ka / Lower Ka
Higher Ka = stronger acid Lower Ka = weaker acid
41
Higher pKa / Lower pKa
Higher pKa = weaker acid Lower pKa = stronger acid
42
Higher pKb / Lower pKb
Higher pKb = weaker base Lower pKb = stronger base
43
Kw expression in terms of Ka and Kb
(Ka)(Kb) = Kw
44
If you warm water, what happens to the Kw, [H+], [OH-] pH, and pOH?
Kw increases [H+]/[OH-] increases pH/pOH decreases
45
Define lewis acids
Lewis acids and electron pair acceptors
46
Define lewis bases
Lewis bases are electron pair donors
47
What happens to pH if you increase the concentration?
pH decreases