Week 1 - Atomic Structure Flashcards

(58 cards)

1
Q

What is an atom?

A

Are the fundamental building blocks for everything.
Can’t see them.
Everything is made of atoms - all matter/physical substances.

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2
Q

What did Dalton believe about atoms?

A

That atoms are unique to each element in their size and mass.
That matter is composed of particles called atoms.
That particles can’t be divided any further.

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3
Q

What is an element?

A

It is a specific type of atom.
They are pure substances - only made of one/the same thing.
Cant be chemically broken down into different forms.
Each element has atoms of their own unique size and mass.

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4
Q

What is a molecule?

A

A group of different atoms chemically bonded together.

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5
Q

What is a chemical reaction?

A

A rearrangement of atoms.

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6
Q

What is a compound?

A

Chemically bonded combination of elements - they combine in fixed proportions.
E.g. h2o.
E.g. sodium chloride

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7
Q

What is a mixture?

A

A physical combination of 2 or more atoms, but they are not chemically bonded together.
E.g. barium sulphate.

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8
Q

How many elects occur in nature?

A

92

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9
Q

How many elements do living organisms contain?

A

20

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10
Q

Who created the periodic table?

A

Medeleev.

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11
Q

What does the period table consist of?

A

All elements.

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12
Q

How are the elements arranged in the periodic table?

A

In periods and groups.
Periods are the rows - left to right.
Groups are the columns - top to bottom.
Elements are arranged in order of increasing atomic mass, left to right.

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13
Q

What will each row (period) have in common?

A

Similar chemical properties.

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14
Q

What will each column (group) have in common?

A

Certain characteristics, e.g. reactivity.

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15
Q

What does each element in the periodic table have on it?

A

An atomic mass.
An atomic number.

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16
Q

Why is tungsten often used in x-ray tubes?

A

It is extremely hard to melt.
Due to a very high melting point.

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17
Q

What was the original atomic structure model, and who made it?

A

Plum pudding model.
JJ Thompson.

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18
Q

What does the plum pudding model suggest about atomic structure?

A

That there are positive and negative charges which mix together in the middle of the atom - giving an overall neutral charge.

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19
Q

How did JJ Thompson discover and create the plum pudding model of atomic structure?

A

He used a negative cathode ray tube, and fired electrons onto a positively charged anode.
This caused the material behind to fluoresce (showing they passed through).

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20
Q

However a new atomic model structure came about -
Who created this new model and what is it called?

A

Rutherford.
Planetary model.

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21
Q

What does Rutherford’s planetary model suggest?

A

That there is a nucleus in the middle of the atom - made up of neutrons and positive protons.
Then all around, in shells, are negatively charged electrons (arranged at certain energy levels).

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22
Q

Where is most of the mass in an atom?

A

The nucleus

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23
Q

How can an atom be neutral?

A

The atom needs the same number of protons as electrons.

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24
Q

What charge, location and mass does a proton have?

A

Charge - +1
Location - the nucleus
Mass - 1.673 x10 to the power of -27
(Is the largest/heaviest subatomic particle -0 but pretty much the exact same as a neutron)

25
What charge, location and mass does a neutron have?
Charge - no charge Location - the nucleus Mass - 1.675 x10 to the power of -27 (Is in the middle)
26
What charge, location and mass does an electron have?
Charge - -1 Location - in shells that orbit the nucleus Mass - 9.109 x10 to the power of -31 (Are the smallest/lightest subatomic particle)
27
What is matter? And what units does matter have?
Mostly empty space. Units of atomic mass units (not kg), as everything is very small. There is mostly empty space in an atom
28
What was Rutherfords experiment to find atomic structure?
He believed alpha particles are made of 2 protons and 2 neutrons - giving an overall charge of 2 (2 positive protons) - e.g. helium. Rutherford believed he found that when alpha particles were fired at an atom, that they either fired straight through if they don’t hit anything (as is mostly empty matter space), or if they hit the nucleus then they bounce of/deflect in different directions. These were with gold foil experiments.
29
There is a strong nuclear force in atoms. What does this do and mean?
It helps the atom stay together. It works by the positive proton charges repel each other, then the neutrons acting as a buffer/spacer.
30
A nuclide is the layout of an atom - shows its symbol, atomic mass and atomic number. It is specific to each element.
31
What is atomic mass?
The total number of protons and neutrons in the nucleus.
32
What is atomic number?
The number of protons. Which is therefore essentially the number of electrons too as they need to be the same to balance the atom and not be an ion.
33
Do electrons make a big difference to atomic mass and why?
They aren’t necessarily included, because they are so small that they don’t really make a difference.
34
What is the atomic number for lead?
82
35
What is the atomic number for tungsten?
74
36
What is the atomic number for molybdenum?
42
37
What is the atomic number for copper?
29
38
What is the atomic number for barium?
56
39
What is the mass number and atomic number for tungsten (W)?
Mass number - 184 (protons + neutrons) Atomic number - 74 (protons / electrons) Number of protons - 74 Number of electrons - 74 Number of neutrons - 110
40
What is an isotope?
A similar version of an element, that has the same number of protons, but a different number of neutrons. So still has the same atomic number. But has a different atomic mass.
41
What is abundance?
The average mass of an element. The average mass number across all isotopes.
42
What location are electrons in, in the atom?
They orbit the nucleus in shells - 3D view - all electrons.
43
What does electrons being in specific shells mean?
That they don’t collide with other electrons.
44
What do the different shells mean?
They have different capacity levels/levels of potential energy. The shells have defined energy levels.
45
How are the shells and their energy levels organised?
The shells further out have more potential energy - can hold more electrons. There are max capacity levels at each shell, as shells go further out they increase capacity. You can’t have free electrons not on a shell. The inner shells have to fully fill first,then fill up as you go further out - so outmost shells may not always fil up completely.
46
What are the shells called, and what are their capacities?
K = shell number 1 = max number of electrons is 2. L = shell number 2 = max number of electrons is 8. M = shell number 3 = max number of electrons is 18. N = shell number 4 = max number of electrons is 32 To work out max number of electrons = 2n squared with n being the shell number.
47
What is an ion?
An unbalanced atom (different amounts of protons and electrons in it).
48
What’s a negative ion?
It is called an anion. The atom has gained an electron.
49
What’s a positive ion?
Called a cation. The atom has lost an electron.
50
True or false - You should assume an atom is neutral and balanced unless told otherwise (Equal number of protons and electrons)
True
51
What is binding/ionisation energy?
There is a force of attraction between the positive nucleus and negative electrons in the shells. They attract to each other (not repel). Binding energy is the energy needed to remove an electron from its shell/atom. (Which is needed for an x-ray). The amount of binding energy needed depends on how many positive protons are in the nucleus, and how close it is to the electron needing to be taken (depends on the strength of that attraction force).
52
What happens to the atom is binding energy is overcome and an electron is removed from its shell in the atom?
The atom is now said to be ionised. It has had a change in its overall charge.
53
What is binding energy measured in?
Electron volts (eV)
54
True or false - For a specific given element and shell, every electron has the same binding energy
True
55
In what 2 ways can an atom be ionised?
With x-rays. Or with electrons.
56
Ionisation of atoms can only occur and remove shell bound electrons if…
… they have enough energy to overcome the binding energy of the whole atom.
57
What can ionisation result in / make the electron go where?…
The electron in the shells can be fully ejected, and then the exiting electron can be deflected out, e.g. after hitting that.
58
What negative outcome may occur in ionisation, to do with electrons being ejected?
The knocked electrons may not have enough force to be fully ejected, but only climb up to a higher shell level - this is bad in x-rays as it can produce a lot of heat (infrared radiation).