atomic and electronic structure Flashcards

(29 cards)

1
Q

name and describe the 7 people/models for the history of the atom

A
  1. Democritus (5th century BC)
    atom was a tiny hard incurable shape
  2. John Dalton (1803)
    Solid sphere. all matter is made of atoms
  3. JJ Thomson (1889)
    Plum pudding model - sphere of positive charge with negatively charged particles scattered
  4. Curie (1911)
    discover radioactivity
  5. Rutherford scattering experiment
  6. Neils Bohr (1913)
    Electrons orbit nucleus in shell, each orbit has a fixed energy
    7.Schrodinger (1926) and Dirac (1928)
    probability to find electrons within space surrounding nucleus. Up to date atomic model
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2
Q

which 3 particles are in an atom and found where?

A

electron - shells orbiting
proton- nucleus
neutron- nucleus

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3
Q

charge of each sub particle

A

proton- +1
electron- -1
neutron - 0

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4
Q

relative mass of each sub particle

A

proton- 1
electron - 1/2000
neutron - 1

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5
Q

6
C
12
which is atomic number and which is atomic mass and what do they show?

A

atomic number - 6 (proton and electron)
atomic mass- 12 (proton+ neutron)

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6
Q

how to work out proton, electron and neutron of an isotope?

A

e.g 1
H
1
would have 1 proton, 1 electron, 0 neutron

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7
Q

working out proton, neutrons electrons of an ion

A

if charge is positive, take electrons away
if charge is negative add electrons
e.g 12
Mg2+
24
has 12 protons, 12 neutrons and 10 electrons

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8
Q

relative atomic mass equation

A

(isotopic mass x relative abundance) + (isotopic mass x relative abundance) / 100

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9
Q

methods to work out % relative abundance

A

tug of war method - work out which more abundant
mathematical method- solve for x

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10
Q

what does heisenbergs uncertainty principle state

A

electrons are found in energy levels called shells
made of sub shells
made of orbitals

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11
Q

what’s a subshell

A

a group of the same type of atomic orbitals in a shell

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12
Q

name the orbitals

A

s p d f

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13
Q

in shell number 1:
sub shell present?
orbitals in subshell?
max number of electrons in each subshell?
man number of electrons in shell?

A

s
1 x s
2
2

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14
Q

in shell number 2:
sub shell present?
orbitals in subshell?
max number of electrons in each subshell?
man number of electrons in shell?

A

s, p
1 x s, 3 x p
2,6
8

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15
Q

in shell number 3:
sub shell present?
orbitals in subshell?
max number of electrons in each subshell?
man number of electrons in shell?

A

s, p, d
1 x s, 3 x p, 5 x d
2,6,10
18

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16
Q

in shell number 4:
sub shell present?
orbitals in subshell?
max number of electrons in each subshell?
man number of electrons in shell?

A

s, p, d, f
1x s, 3 x p, 5 x d, 7 x f
2,6,10,14
32

17
Q

shape of s orbital

18
Q

shape of p orbital

A

dumbell ( infinity sign)

19
Q

how many electrons can fit in an orbital?

20
Q

how many electrons in s subshell

21
Q

how many electrons in p subshell

A

6 (3 orbitals, 2 e- in each)

22
Q

how many electrons in d subshell

A

10 ( 5 orbital per subshell, 2 e- in each)

23
Q

how many electrons in f subshell

A

14 (7 orbitals, 2e- in each)

24
Q

how do boxes get filled in orbitals?

A

fill individually with arrows then add a double

25
the aufbau principle
electrons fill orbitals of lowest energy first
26
electron filling order ( configuration)
1s2, 2s2, 2p6, 3s2, 3p6, 4s2, 3d10, 4p6, 4d10, 4f14
27
what groups in periodic table are each block (spdf) and what’s it mean
s- group 1 and 2 p- group 3,4,5,6,7,8 d- transition metals f-ionthanoids when writing electron structure it will finish in that block
28
electron configuration anomalies on the first row of d block why?
Cr - 3p6,4s1,3d5 Cu- 3p6,4s1,3d10 make atom more stable
29
m/z values are for
a single charged positive ion