1
Q
NaOCl, TEMPO
A
mild oxidation
2
Q
NaOCl, AcOH
A
strong oxidation
3
Q
CrO3, H3O+
A
strong oxidation
4
Q
DMP
A
mild oxidation
5
Q
excess NaOCl, TEMPO
A
strong oxidation
6
Q
KMnO4
A
strong oxidation
7
Q
PCC, CH2Cl2
A
mild oxidation
8
Q
Na2Cr2O7, H2SO4
A
strong oxidation
9
Q
SWERN (DMSO, (COCl)2, NEt3)
A
mild oxidation
10
Q
HNO3
A
strong oxidation
11
Q
reduction of ketones and aldehydes
A
NaBH4 (include H3O+ or something)
12
Q
reduction of ketones, aldehydes, esters, and acid anhydrides
A
LiAlH4 (include H3O+ or something)
13
Q
what type of alcohols does TsCl/pyridine work with
A
primary and secondary
14
Q
what mechanism does TsCl/pyridine use
A
SN2
15
Q
2 ways to reduce alcohols
A
- H2SO4, heat, H2, Pt
- TsCl, pyridine, LiAlH4
16
Q
mechanism of adding HBr or HCl to alcohol
A
- primary: SN2
- secondary/tertiary: SN1, SN1
17
Q
fastest Lucas reagent alcohol
A
tertiary
18
Q
oxidation
A
- addition of O/O2
- addition of X2
- loss of H2
19
Q
reduction
A
- loss of O/O2
- loss of X2
- loss of H2
Ochem
flashcards
Decks in class (22)
# Cards
