Chapter 16 - Fire/Explosion Flashcards

(61 cards)

1
Q

The combination of oxygen with other substances to produce new chemical products is called _____ .

A

oxidation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

True or False: All oxidation reactions yield carbon dioxide and water as products.

A

False

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

_____ is the capacity for doing work.

A

energy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

Burning methane to heat water and thus produce steam for the purpose of driving a turbine is an example of converting _____ energy to _____ energy to _____ energy.

A

chemical;
heat;
mechanical

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

The quantity of heat evolved from a chemical reaction arises out of the _____ and of chemical bonds.

A

breaking; formation

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

Molecules must _____ energy to break their bonds and _____ energy when their bonds are reformed.

A

absorb; liberate

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Excess heat energy liberated by an oxidation reaction is called the _____ .

A

heat of combustion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

True or False: All reactions require an energy input to start them.

A

ture

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

The minimum temperature at which a fuel burns is known as the _____ temperature.

A

ignition

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

A fuel achieves a sufficient reaction rate with oxygen to produce a flame only in the _____ state.

A

gaseous

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

The lowest temperature at which a liquid fuel produces enough vapor to burn is the _____ .

A

flash point

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

_____ is the chemical breakdown of a solid material to gaseous products.

A

pyrolysis

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

The _____ defines the upper and lower limits between which a mixture of gaseous fuel and air burns.

A

flammable range

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

_____ is a phenomenon in which a fuel burns without the presence of a flame.

A

glowing combustion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

True or False: The rate of a chemical reaction increases as the temperature rises.

A

True

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

_____ describes a fire caused by a natural heat-producing process in a poorly ventilated area.

A

spontaneous combustion

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
17
Q

True or False: An immediate search of a fire scene can commence without obtaining a search warrant.

A

True

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
18
Q

A search of the fire scene must focus on finding the fire’s _____ .

A

origin

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
19
Q

True or False: The origin of a fire is most likely to be located closest to the lowest point that shows the most intense characteristics of burning.

A

True

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
20
Q

A portable _____ detector can suck in the air surrounding a questioned sample to rapidly screen for the presence of volatile residues at fire scenes.

A

vapor

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
21
Q

True or False: The collection of debris at the origin of a fire should include all nonporous materials.

A

False

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
22
Q

_____ containers must be used to package all materials suspected of containing hydrocarbon residues.

A

airtight

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
23
Q

True or False: Substrate controls should be collected at a fire scene from an area where it can be reasonably assumed that no flammable substance was placed.

A

True

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
24
Q

A(n) _____ is a mechanism consisting of a glass bottle containing flammable liquid with a cloth rag stuffed into it and lit as a fuse.

A

Molotov cocktail

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
25
The simplest way to recover accelerant residues from fire-scene debris for identification is to heat the airtight container in which the sample is packaged and remove the _____ with a syringe.
headspace
26
The most sensitive and reliable instrument for detecting and characterizing flammable residues is the _____ .
gas chromatography
27
Complex chromatographic patterns can be simplified by passing the components emerging from the gas chromatographic column through a(n) _____ .
mass spectrometer
28
Rapid combustion accompanied by the creation of large volumes of gases describes a(n) _____ .
explosion
29
True or False: Chemicals that supply oxygen are known as oxidizing agents.
True
30
Explosives that decompose at relatively slow rates are classified as _____ explosives.
low
31
The speed at which low explosives decompose is called the speed of _____ .
deflagration
32
Three ingredients of black powder are _____ , _____ , and _____ .
potassium nitrate; charcoal; sulfur
33
_____ explosives detonate almost instantaneously to produce a smashing or shattering effect.
high
34
The most widely used low explosives are _____ and _____ .
black powder; smokeless powder
35
A low explosive becomes explosive and lethal only when it is _____ .
confined
36
True or False: Air and a gaseous fuel burn when mixed in any proportions.
False
37
High explosives can be classified as either _____ or _____ explosives.
primary; secondary
38
The most widely used explosive in the military is _____ .
RDX
39
The explosive core in detonating cord is _____ .
PETN
40
A high explosive is normally detonated by a(n) _____ explosive contained within a blasting cap.
initiating
41
An obvious characteristic of a high explosive is the presence of a(n) _____ at the origin of the blast.
crater
42
To screen objects for the presence of explosive residues in the field or the laboratory, the investigator may use a handheld _____ .
ion mobility spectrometer
43
Unconsumed explosive residues may be detected in the laboratory through a careful examination of the debris.
microscopic
44
True or False: Debris and articles at an explosion scene that are collected from different areas are to be packaged in separate airtight containers.
True
45
Which substance has the highest ignition temperature?
Benzene
46
The rapid combination of oxygen with a fuel that results in a noticeable release of energy is called what?
Combustion
47
The minimum temperature at which a liquid fuel will produce enough vapor to burn is called the what?
Flash point
48
Which instrumentation is considered the most sensitive and reliable for detecting and characterizing flammable residues?
GC
49
What is the decomposition of organic matter by heat called?
Pyrolysis
50
Which chemical reaction is associated with a fire?
Oxidation
51
Which of the following cannot be determined from a laboratory examination of evidence recovered from an arson?
The brand name of gasoline used to start the fire.
52
Which of the following can be determined from a laboratory examination of evidence recovered from an arson?
The presence of accelerate agent in debris The ignition mechanism (used by arsonist) Origin of liquid gasolines
53
The heat generated in a chemical reaction comes from what?
Breaking and formation of chemical bonds
54
Combustion that occurs at the surface of a solid is known as what?
Glowing combustion
55
T or F: Primary explosives are stable.
False
56
T or F: Black powder a high explosive
False
57
Most explosives can be recovered from debris for future study by being rinsed with what?
Acetone
58
What's the homemade explosive that has been used by terrorist organizations in the Middle East?
TATP
59
What method is used to screen objects for the presence of explosive residues?
Ion-mobility spectrometry
60
Which of the following explosive materials is available in commercial form as fertilizer?
Ammonium nitrate
61