Dynamic equilibrium occurs when
evaporation and condensation happen at equal rates.
Vapor pressure increases with
temperature
The vapor pressure of a liquid depends strongly on
the strength of its intermolecular torces.
Liquids with high vapor pressure evaporate _____ and have ____ intermolecular forces
easily, weak
Liquids with low vapor pressure have
have strong intermolecular forces, such as strong London dispersion forces or strong dipole-dipole forces
Intermolecular forces are
forces of attraction that exist between molecules.
Intramolecular forces
exist within a molecule.
Which is stronger, intermolecular or intramolecular
Intramolecular because chargers are larger and closer together
lon-ion interactions occur between
oppositely charged ions in ionic compounds.
These interactions are very strong, giving ionic compounds high melting and boiling points.
Dipole-dipole interactions occur between
polar molecules due to their partial positive (St) and partial negative (8) charges.
Hydrogen bonding is a
yery strong dipole-dipole interaction that occurs when hydrogen is bonded to F, 0, or N.
These elements strongly attract electrons, making hydrogen highly positive
Responsible for the unusually high boiling and melting points of water
Dispersion forces are the
weakest kind of intermolecular attraction and occur between all molecules. They are caused by the motion of electrons, which can temporarily create uneven electron distributions.
Viscosity is the
resistance of a liquid to flow caused by intermolecular attractions.
Liquids with weaker intermolecular forces have ____ viscosity, and flow more easily
lower
while liquids with stronger intermolecular forces have ____ viscosity. and flow more slowly.
higher
Surface tension is
the energy required to increase the surface area of a liquid.
The viscosity of a liquid ____ as temperature increases.
decreases
Surface tension ____ as temperature increases because molecules gain enough kinetic energy to counteract attractive forces.
decreases
Capillarity is the
ability of a liquid to rise in a narrow tube against gravity.
Surface tension ____ as temperature increases because molecules gain enough kinetic energy to counteract attractive forces.
decreases
Concave meniscus occurs when
adhesive forces are stronger than cohesive forces, causing the liquid to climb the container walls (e.g., water)
Convex meniscus occurs when
cohesive forces are stronger than adhesive forces, causing the liquid to form a dome shape (e.g., mercury due to metallic bonding)
Vaporization is the phase change in which a
substance changes from liquid to gas. It can occur through boiling or sublimation.