What is the composition of dentine?
70% hydroxyapatite
20% organic material, mainly collagen
10% water
Tubules around 1-5μm width
Why resin bond to dentine?
What are the problems of bonding to dentine?
How can we fix the smear layer?
How can we bond hydrophobic resins to hydrophilic dentine?
with the use of Hydroxyl groups -OH Carboxyl groups -COOH phosphate groups -P-(OH)3 - these bond with the amino groups in the collagen and the hydroxyl groupss in hydroxyapatite
What are dentine primers made of?
A bifunctional monomer:
A polar group
A spacer
A methacrylate group
-A solvent or water to carry the monomer deep into the demineralised collagen
How to prevent fluid flow in tubules?
We now have a surface of hydrophobic methacrylate groups
Bond directly using methacrylate based resin
What is dentine sealer?
Methacrylate based
Either light cured or chemically cured
Can contain some bifunctional monomer to aid bonding with the primer
What are the 3 stages to dentine bonding?
What are the concerns with dentine bonding?
Eliminate the marginal gap (due to polymerisation shrinkage)
wet dentine bonding
What happens if you thoroughly dry dentine?
collagen collapses
volatile solvent in primer chases water out of collagen and brings in the bifunctional monomer
What are the 4 types of dentine bonding agents?
Type 1 - etch, prime, seal
Type 2 - etch, prime and seal
Type 3 - etch and prime, seal
type 4 - etch and prime and seal
What is the prime and bond NT?
Give an example of a prime and bond NT
What do self etching primers do? (type 3)
Acidic monomers that etch and prime
The smear layer is dissolved, but not removed, collagen demineralised and infiltrates the collagen network
What are the benefits of self etching primers?
- can prevent marginal staining (caused by weak etching of enamel) by pre-etching enamel with phosphoric acid
Which type of bonding agent has the weakest bonds?
Type 4 - all in one
How do all in one systems work?
..
Which type of dentine bonding agent to use?
Type 1’s are the most difficult to use and require excellent technique
Type 2’s are almost equally difficult and the bond strength is (generally) worse
Type 3’s are quite simple to use and have good bond strength
Type 4’s are currently unpredictable as they are still quite new
What is usually used as a dentine conditioner?
EDTA, Maleic acid, oxalis acid, phosphoric acid, nitric acid
What ideal properties should a direct aesthetic restorative material have?
Safe for dental team and patient Aesthetic Durable, chemically stable and tasteless Poor conductor of heat Minimal tooth preparation Easy to use Cost effective
What is the composition of dental composite resins?
The matrix component is typically a mixture of methacrylate resins (most commonly bis glycidyl methacrylate or bisGMA formed by the reaction of glycidyl methacrylate with bis-phenol A).
The filler is typically a silica (SiO2) powder.
Modern dental composites usually contain a photoinitiator (most commonly camphorquinone).
What can dental composites be set by?
Chemical cure or light cure
How does the chemical cure happen?
In chemical cure, two pastes are mixed (an activator with a free-radical initiator) but this approach is effectively obsolete in restorative materials.