What reaction is GIC made from?
acid-phase reaction with 3 phases
What are the 3 phases of the acid-base reaction?
Dissolution (acidic attack of glass surface)
Gelation (early cross-linking by Ca++)
Hardening (substitution of Ca++ by Al+++)
gives salt and water
What makes GIC very soluble?
All the COOH groups together in the long chain polyacid
What are the properties of GIC?
Why can GIC adhere to the tooth?
GIC has acid degraded particles (calcium) - form salt bridges with the calcium in the tooth tissue
What are the clinical uses for GICs?
What are the contra-indications for GIC?
Highly loaded sites or incisal edge
or where aesthetics are important
What is a glass Carbomer?
Documented as a heat cured material and marketed as a potential alternative to GICs with similar indications of use
what mechanisms may make fluoride antibacterial?
effects on metabolism via enolase inhibition and/or metabolic toxicity
When may fluoride not be antibacterial?
when microorganisms are protected within a biofilm.
How does fluoride ion exchange work?
Which hybrid biomaterials are treated as a GIC?
GIC
Cermet glass PVP carbomer
RM- GIC
Which hybrid biomaterials are treated as a composite resin?
GIomer
Compomer
Ormocer
Composite resin
How is a RM-GIC different to GIC?
Like a Glass-ionomer but with the addition of a water miscible monomer hydroxyethylmethacrylate (HEMA) and a photoinitiator
sets with both an acid-base reaction and photo-polymerisation
shares GIC chemical bond to untreated dentine
How does Dyract AP release fluoride?
Needs to absorb water before it can release fluoride