Enthalpy Flashcards

(27 cards)

1
Q

What is enthalpy a measure of?

A

The heat energy in a chemical system

The chemical system refers to the atoms, molecules, or ions making up the chemicals.

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2
Q

Can enthalpy be measured directly?

A

No

However, enthalpy changes can be measured.

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3
Q

What is the formula for enthalpy change (ΔH)?

A

ΔH = H(products) - H(reactants)

This formula indicates the difference in enthalpies between reactants and products.

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4
Q

ΔH can be positive or negative depending on what?

A

Whether the products contain more or less energy than the reactants

A positive ΔH indicates endothermic reactions, while a negative ΔH indicates exothermic reactions.

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5
Q

What does the law of conservation of energy state?

A

Energy cannot be created or destroyed

This fundamental rule of science applies to chemical reactions involving enthalpy changes.

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6
Q

In a chemical reaction, what is the system?

A

The chemicals - the reactants and products

The surroundings include everything that is not the chemical system.

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7
Q

What is an exothermic change?

A

Energy transfer from the system to the surroundings

This type of change releases heat.

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8
Q

What is an endothermic change?

A

Energy transfer from the surroundings to the system

This type of change absorbs heat.

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9
Q

What do enthalpy profile diagrams show?

A

The relative enthalpies of the reactants and products and the enthalpy change ΔH

These diagrams visually represent the energy changes during a reaction.

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10
Q

What is enthalpy a measure of?

A

The heat energy in a chemical system

The chemical system refers to the atoms, molecules, or ions making up the chemicals.

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11
Q

Can enthalpy be measured directly?

A

No

However, enthalpy changes can be measured.

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12
Q

What is the formula for enthalpy change (ΔH)?

A

ΔH = H(products) - H(reactants)

This formula indicates the difference in enthalpies between reactants and products.

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13
Q

ΔH can be positive or negative depending on what?

A

Whether the products contain more or less energy than the reactants

A positive ΔH indicates endothermic reactions, while a negative ΔH indicates exothermic reactions.

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14
Q

What does the law of conservation of energy state?

A

Energy cannot be created or destroyed

This fundamental rule of science applies to chemical reactions involving enthalpy changes.

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15
Q

In a chemical reaction, what is the system?

A

The chemicals - the reactants and products

The surroundings include everything that is not the chemical system.

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16
Q

What is an exothermic change?

A

Energy transfer from the system to the surroundings

This type of change releases heat.

17
Q

What is an endothermic change?

A

Energy transfer from the surroundings to the system

This type of change absorbs heat.

18
Q

What do enthalpy profile diagrams show?

A

The relative enthalpies of the reactants and products and the enthalpy change ΔH

These diagrams visually represent the energy changes during a reaction.

19
Q

Why is there so many different types of enthalpy change of reaction?

A

For each reaction there are different conditions as each reaction is different, so scientists created specific tightly defined enthalpy changes where only one thing varies

20
Q

What are the standard conditions?

A

Standard pressure is 100 kilopascals
Standard temperature is 298 k. 25 C.
Standard concentration is 1 moldm -3
Standard state is physical state of substance under standard condition

21
Q

What is standard enthalpy change of reaction?

A

Enthalpy change that accompanies a reaction in the molar quantities shown in a chemical equation under standard conditions with all reactions and products in their standard States

22
Q

What is enthalpy change of formation?

A

Standard enthalpy change of formation is enthalpy change that takes place when ONE mole of a compound is formed from its ELEMENTS under standard conditions

23
Q

What is standard enthalpy change of combustion

A

Enthalpy change that takes place when ONE mole of a substance reacts COMPLETELY with oxygen under standard conditions
REACTS COMPLETELY SO PRODUCES CO2

24
Q

What is standard enthalpy change of neutralisation?

A

Energy change that accompanies the reaction of an acid by a base to form mole of H2O liquid under standard conditions
- involves the reaction of H+ with oh minus both aqueous to form one mole of water liquid

25
What is the equation for heat energy and units? Centimetre cubed to gram
Q = MC Delta T Heat energy equals mass times specificity, capacity times by change in temperature Heat energy equals joules Mass equals grams Specific capacity equals Jg -1 K -1 Temperature equals Kelvin 1 cm cubed equals 1 g
26
What is the specificity for water?
Specific heat capacity for water is 4.18 J g -1 K -1
27
What is the equation for enthalpy change?
Enthalpy change equals energy divided by moles And they'll be changed is measured in kj/mole Energy is measured in kilojoules Moles is measured in mole