Flowchart v2 Flashcards

(21 cards)

1
Q

What is the product when 1o R–X reacts with Conc NH3?

A

RNH2

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2
Q

What does SOCl2 convert 1o R–OH into?

A

1o R–X

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3
Q

What is the major product when RC=CH2 reacts with dil(?) H2SO4/H2O?

A

2o R–OH

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4
Q

Fill in the blank: Sayseff’s rule states that hydrogen is removed from the C atom with the least number of _______.

A

H atoms

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5
Q

What reagent is used to convert RCHO to RCOOH?

A

H+/Cr2O72- reflux OR H+/MnO4-

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6
Q

True or False: Conc NH3 can convert 2o R–X to R–NH2.

A

True

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7
Q

What is the primary product when R–C–OH is treated with NaBH4?

A

2o R–OH

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8
Q

What happens when R–C–O– is treated with H2O?

A

RCOO– (base hydrolysis)

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9
Q

What is the color change observed when using Tollen’s reagent on an aldehyde?

A

Formation of a silver mirror or grey deposit

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10
Q

When RC=CH2 reacts with OH-(alc), what is the product?

A

RC=CH2

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11
Q

What is produced when R–C–R’ reacts with H+/Cr2O72- reflux?

A

RCOOH

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12
Q

What does the addition of HX to RC=CR’ yield?

A

2o R–X

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13
Q

Fill in the blank: Markovnikov’s rule states that hydrogen is removed from the C atom with the least number of _______.

A

H atoms

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14
Q

What is the effect of Conc H2SO4 on 1o R–OH?

A

It converts it to RC=CH2

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15
Q

What occurs when RCOOH is treated with SOCl2?

A

RCOCl

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16
Q

What reaction occurs when 1o R–OH is distilled with H+/Cr2O72-?

17
Q

What is the color change in Fehling’s reagent when an aldehyde is oxidized?

A

Blue CuSO4 to brick red Cu+ solid

18
Q

What is the result of base hydrolysis on RCOOR?

19
Q

What happens when R–C–Cl is treated with H2O?

20
Q

What is the chemical reaction when R’COOH is treated with R’OH and conc H2SO4?

21
Q

What does the addition of H+ / MnO4- to RCHO produce?