Isotopes
Atoms of the same element (same number of protons and electrons) with different numbers of neutrons.
Relative isotopic mass
Mass (of an isotope) compared to 1/12th of the mass of carbon-12
Relative atomic mass
Weighted mean mass of an element compared with 1/12th of the mass of carbon-12
Mass Spectrometry: Ionisation
Gaseous particles are injected into the spectrometer and hit by a high energy beam of electrons. This causes them to become positive ions.
x_(g) + e^- —> x^+ + 2e^-
Mass Spectrometry: Acceleration
Particles are then accelerated by a magnetic field.
Mass spectrometry: Drift Region
Through the drift region, particles travel at different speeds (as heavier ions move more slowly), so separate and hit the ion detector at different times.
The ion detector then detects the ions when they arrive, and feeds a signal into a computer, producing relative abundance of ions against the mass/charge ratio (mass/1+)
Relative Atomic Mass Equation
(%isotopic mass+%isotopic mass)/100
Do you always divide by 100 when finding RAM?
Not when multipliers don’t sum 100%
Ammonium ion
NH4^+
Hydroxide ion
OH^-
Nitrate
NO3^-
Nitrite
NO2^-
Hydrogencarbonate
HCO3^-
Permaganate/Maganate(VII)
MnO4^-
Carbonate
CO3^2-
Sulphate
SO4^2-
Sulphite
SO3^2-
Dichromate(VI)
Cr2O7^2-
Phosphate
PO4^3-
Silver
Ag+
Zinc
Zn2+