What is relative molecular mass (Mr) and relative formula mass?
Weighted mean mass of a molecule/formula unit compared to 1/12th of an atom of carbon-12.
Molecular = covalent
Formula = ionic
Avogadro constant
6.02*10^23, or the number of particles in a mole of substance.
Amount of substance
Quantity of a chemical substance
Explain term ‘mole (mol)’
The SI unit of amount of substance. One mole
contains 6.02*10^23 ‘elementary entities’ (things: particles/ions/atoms/molecules/oranges)
Explain term ‘molar mass’
The mass in grams of 1 mole of particles (grams per mol, gmol^-1)
How do you figure out molar mass?
Relative formula/molecular mass in grams = 1 mole.
Explain the term ‘molar gas volume
The volume occupied by one mole of gas (volume per mole, dm^3mol^-1)
Empirical formula
The simplest whole number ratio of atoms of each element present in a compound.
Molecular formula
Number and type of atoms of each element in a molecule.
Calculating empirical/molecular formulae from %mass/mass/Mr
anhydrous crystals
Ionic solid containing no water molecules
hydrated crystals
Ionic solid containing water molecules
water of crystallisation
Water molecules in an ionic solid
Formula of hydrated salt from given percentage/mass composition
1) calculate mass water lost
2) convert residual mass and water mass to moles
3) write as ratio
4) write as whole number ratio
Equation involving mass, moles and molar mass?
n = m/M
mass/molar mass = moles
Equation involving concentration, moles, and volume?
n = cV
Moles = concentration*volume
The Ideal Gas Equation?
pV = nRT
pressurevolume = molesgas constant*temperature
Units in the Ideal Gas Equation?
Pressure = Pascals
Volume = m^3
n = mol
Temperature = Kelvin (C+273)
What volume is a gas at RTP?
24dm^3
What is pressure and temperature at RTP?
Pressure: 101 kPa
Temperature: 293K (20C)
Stoichiometry
Ratio of moles in an equation
Percentage Yield equation
(actual mass of product /theoretical mass of product)*100
Atom economy equation
(Mr desired product(s)/Mr total product(s))*100
Benefits for sustainability of developing chemical processes with a high atom economy?
-Lower amounts of reactant needed
-Less energy needed for obtaining raw materials
-Less energy needed for process (less processes for more useful product)
-Less waste products produced/to deal with
-Less energy needed for disposing of waste products