Module 2 Chapter 3 Flashcards

Amount of Substance (27 cards)

1
Q

What is relative molecular mass (Mr) and relative formula mass?

A

Weighted mean mass of a molecule/formula unit compared to 1/12th of an atom of carbon-12.

Molecular = covalent
Formula = ionic

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2
Q

Avogadro constant

A

6.02*10^23, or the number of particles in a mole of substance.

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3
Q

Amount of substance

A

Quantity of a chemical substance

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4
Q

Explain term ‘mole (mol)’

A

The SI unit of amount of substance. One mole
contains 6.02*10^23 ‘elementary entities’ (things: particles/ions/atoms/molecules/oranges)

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5
Q

Explain term ‘molar mass’

A

The mass in grams of 1 mole of particles (grams per mol, gmol^-1)

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6
Q

How do you figure out molar mass?

A

Relative formula/molecular mass in grams = 1 mole.

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7
Q

Explain the term ‘molar gas volume

A

The volume occupied by one mole of gas (volume per mole, dm^3mol^-1)

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8
Q

Empirical formula

A

The simplest whole number ratio of atoms of each element present in a compound.

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9
Q

Molecular formula

A

Number and type of atoms of each element in a molecule.

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10
Q

Calculating empirical/molecular formulae from %mass/mass/Mr

A
  1. Take (%) mass of each element present, and divide by Mr to find moles of each element
  2. Simplify ratio by dividing by lowest mole
  3. Round/multiply (if ABSOLUTELY necessary) to whole numbers
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11
Q

anhydrous crystals

A

Ionic solid containing no water molecules

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12
Q

hydrated crystals

A

Ionic solid containing water molecules

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13
Q

water of crystallisation

A

Water molecules in an ionic solid

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14
Q

Formula of hydrated salt from given percentage/mass composition

A

1) calculate mass water lost
2) convert residual mass and water mass to moles
3) write as ratio
4) write as whole number ratio

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15
Q

Equation involving mass, moles and molar mass?

A

n = m/M

mass/molar mass = moles

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16
Q

Equation involving concentration, moles, and volume?

A

n = cV

Moles = concentration*volume

17
Q

The Ideal Gas Equation?

A

pV = nRT

pressurevolume = molesgas constant*temperature

18
Q

Units in the Ideal Gas Equation?

A

Pressure = Pascals
Volume = m^3
n = mol
Temperature = Kelvin (C+273)

19
Q

What volume is a gas at RTP?

20
Q

What is pressure and temperature at RTP?

A

Pressure: 101 kPa
Temperature: 293K (20C)

21
Q

Stoichiometry

A

Ratio of moles in an equation

22
Q

Percentage Yield equation

A

(actual mass of product /theoretical mass of product)*100

23
Q

Atom economy equation

A

(Mr desired product(s)/Mr total product(s))*100

24
Q

Benefits for sustainability of developing chemical processes with a high atom economy?

A

-Lower amounts of reactant needed
-Less energy needed for obtaining raw materials
-Less energy needed for process (less processes for more useful product)
-Less waste products produced/to deal with
-Less energy needed for disposing of waste products

25
What is a Limiting Reagent and how does this factor into equations?
A limiting reagent is the reactant completely consumed in a chemical reaction when reagents are not in stoichiometric amounts - the other reactant is in excess. You should use the limiting reagent for calculations - determine which is limiting using moles and a balanced equation. (If reagent A has x moles, how many moles does reagent B need to have to react fully? )
26
What are two methods to collect gas in experiments?
1) Collecting a gas over water: a bung with a delivery tube is fed into a measuring cylinder held upside down in a water trough 2) Collecting gas in a gas syringe
27
In which situations would you use different methods of collecting gas?
1) collecting gas over water: with large volumes of a gas that doesn’t dissolve in water 2) gas syringe: with smaller volumes of gas