what unit of angle do we use?
radians
what is the equation for shear strain?
γ = u/l0
what is the equation for shear modulus?
shear stress / shear strain
what is the symbol for shear modulus?
G
what is the symbol for bulk modulus?
K
what is the equation for bulk modulus?
K = -P / (ΔV/V0)
what are the methods of obtaining Young’s modulus?
vibration frequency
speed of sound
what does stiffness of a solid depend on?
stiffness of chemical bonds
number of bonds across loaded section
direction of loading relative to direction of the bonds
what does anisotropic mean?
different physical properties in different directions
what is equation for change in bond energy?
dU = F dr
F = force
dr = change inn distance
what does bond stiffness relate to?
proportional to melting point of the bond
what is the order of bond stiffness values?
covalent
metallic
ionic
hydrogen
van der waals
what are the equations for Young Modulus?
E = k/r0 = 1/r0 * (dF/dr)(subscript r0)
r0 = equilibrium bond length
k = bond stiffness
F = force
what does Young modulus depend on?
chemical bond strength
what is Young’s modulus like for polymers?
has a large temperature dependence
how do we predict E for polymers at low temperatures?
using simple van der waals forces
what is E like for polymers at high temperatures and why?
much lower
van der waals linking polymer chains together are easily broken by thermal motion of molecules
where is elastic limit for polymers?
can be much higher than linear portion of stress strain curve
what is the transition between low and high temperatures?
glass transition temperature
what is the symbol for glass transition temperature?
T subscript g
what can happen to polymers above Tg?
become leathery, rubbery, viscous