Winterization of fats
process to produce salad oils that do not crystallize (cloudy) at refrigerator temps
Oils can become cloudy at lower temps because ..
some of the triglyceride molecules crystallize and become solid
Winterization of fats involved lowering the ..
temp of oil too a point at which the triglycerides with high melting points crystallize
The oil is filtered to remove the crystals the ..
the reaming oil has a lower melting point and does not crystallize at refrigerator temp
The chemical spoilage that commonly occurs with fats and fatty foods is called
rancidity
Highly unsaturated fats/oils such as polyunsaturated fats are much more..
susceptible than saturated or monounsaturated fats (nuts, wheat germ, whole wheat flour highly susceptible)
2 types of rancidity
- hydrolytic rancidity
Oxidative rancidity
occurs primarily with unsaturated fatty acid portions of triglycerides that are susceptible to oxidative changes. often results from a self-perpetuating chemical chain reaction.
Oxidative reaction begins with the ..
addition of oxygen to carbon atoms next to a double bond in a fatty acid. The reaction results in formation of hydro peroxide.
During oxidative reactions, Hydroperoxide molecules readily breakdown into..
volatile products that have off odours and flavours characteristic of rancid fat.
Oxidative damage can be ..
prevented or slowed down through use of antioxidants
Hydrolytic rancidity
involves breaking of chemical bonds and in the process the addition of water. result of the breaking of triglycerides structure composed of short chain FA. Results in the production of glycerol and free short chain fatty acids such as butyric acid and caproic acid.
Importance of fats/oils in foods
Fat replacers
Products or ingredients that can replace part or all of the functions of fat in foods, and may/may not provide energy.
It is difficult to find a fat substitute that will..
perform well in all food products
How to reduce fats in foods
Mouthfeel of fat
Fat plasticity
Carbohydrate-based replacers includes..
Includes derivatives of cellulose, maltodextrins, gums, modified starches and polydextrose.
Carbohydrate based replacers function as..
thickeners and stabilizers and when used to replace fat they add form and structure and act as emulsifiers when small amount of fat is present in the food.
Carbohydrate based replacers produce ..
a mouthfeel that is similar to that associated with fat but they do not taste like fat and do not function like fat in cooking. (ex: Oatrim (made from hydrolyzed oat flour)
Protein based replacements
Simplesse process
produces protein particles so small that they are perceived as fluid by mouth.
Fat based replacements