Transition elements Flashcards

(35 cards)

1
Q

What are chelates

A

bonding of polydentate ligand to metal ion through more than one site

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2
Q

What are the anomalies in binding energy

A

Cr and Mn as their metallic structure is different

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3
Q

What are the complementary colours of the following
orange
red
violet

A

orange - blue
red - yellow
violet - green

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4
Q

what ions give colourless compounds

A

The ions with zero unpaired electrons
Zn+2, Ti+4, Cu+, Sc+3

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5
Q

what colour do ions with one paired electrons give:
Ti+3, Cu+2

A

Ti gives purple and copper gives blue

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6
Q

What colour do ions with two unpaired electrons give
V+3, Ni+3

A

V gives green and Ni gives green

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7
Q

What colour do ions with three unpaired electrons give
Cr+3, Co+2

A

Cr gives deep green and Co gives pink

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8
Q

What colour do ions with four unpaired electrons give
Cr+2, Fe+2

A

Cr+2 gives blue and Fe gives green

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9
Q

What colour do ions with five unpaired electrons give
Fe+3

A

yellow

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10
Q

Which elements show maximum oxidation state

A

Ru and Os with +8

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11
Q

What is the most common oxidation state in 3d

A

+2

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12
Q

Which element has the max oxidation state in 3d

A

Manganese with +7

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13
Q

In 3d which oxidation is most common in the beginning and ending of transition element

A

in begin its +3 and end +2

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14
Q

Which element has max range of oxidation state

A

Mn

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15
Q

Which catalyst is used in the ziegler-natta polymerization

A

TiCl4

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16
Q

Which catalyst is used in the wacker process

A

Cu to convert ethylene to acetylaldehyde

17
Q

Which elements poison nickel catalyst

A

Pb and arsenic

18
Q

In T.E which element has max ionization energy

19
Q

Which element has min ionization energy in T.E

20
Q

arrange following alloys of iron in ascending order of carbon content
cast iron, steel, wrought

A

wrought, steel, cast iron

21
Q

What is the most abundant T.E

22
Q

What magnetism do Fe, Co and Ni show

A

ferromagnetism

23
Q

What are Pt, Pb, Rh called

24
Q

What elements are in earth’s crust

A

Aluminum, oxygen and silicon

25
What is fool's gold
pyrite or iron sulphide
26
what is richest ore of iron
magnetite
27
How do you name complex compounds
1.first comes the cation which is mentioned first 2. then number of ligand and ligand half name 3. then central atom eg K[Fe(Cn)6] so potassium hexacyanoferrate
28
which elements usually give linear shape in 2 coordination
Cu, Ag, Au
29
Which compound gives bent arrangement in 2 coordination
[Ag(SCN)]
30
What are 4 coordinated tetrahedral complex ions
CuCl4 and CoCl4
31
What is a 4 coordinated square planar complex
cisplatin [Pt(Cl)2(NH3)2] cis-diamminedichloroplatinum
32
What complexes have octahedral shape
6 coordinated
33
What are non typical transition elements
elements which do not have half filled orbitals in any ionic state
34
what are non typical transition elements
Group IIB (Zn, Cd, Hg) Group IIIB (Sc, Y, La)
35
What oxidation state to typical transition elements show
non variable