C9 Flashcards

(38 cards)

1
Q

Why is carbon useful for making large compounds?

A

Because each carbon atom can make four strong bonds. Most commonly with other carbon atoms or hydrogen atoms.

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2
Q

What are hydrocarbons?

A

Any compound that is ONLY formed from carbon and hydrogen.

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3
Q

What are the first 5 alkANEs? (Monkeys Eat Purple Blueberries Politely)

A

Methane, Ethane, Propane, Butane, Pentane.

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4
Q

What is a homologous series?

A

(A group of organic compounds with the same general formula), similar chemical properties (so react in a similar way) and gradual variation in physical properties.

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5
Q

What is a key feature of alkanes (regarding their bonds)?

A

They are SATURATED COMPOUNDS.
- Every carbon atom has four single covalent bonds.
- There aren’t any double bonds.

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6
Q

What are trends as the length of carbon trend increases in alkanes?

A

Boiling point increases.

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7
Q

What state are the first four alkanes?

A

Shorter alkanes are usually gas at room temp.

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8
Q

What state are longer alkanes (5-17 carbon atoms)?

A

Liquid at room temp.

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9
Q

What state are really long chain alkanes (18+)?

A

Could be potentially solid at room temp.

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10
Q

What is a physical property of shorter alkanes?

A

More volatile- evaporate more easily due to really low boiling point.
More flammable- easier to ignite/ burn.

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11
Q

What is a physical property of longer alkanes?

A

More viscous- thick and sticky, honey like consistency.

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12
Q

What is a main use of hydrocarbons?

A

For fuel, as they release loads of energy when they’re burnt with oxygen.

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13
Q

Equation for complete combustion of hydrocarbons?

A

Hydrocarbon + oxygen —> CO2 + H2O

  • hydrogen and carbon are each oxidised to form CO2 and H2O.
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14
Q

What type of reaction is the complete combustion of hydrocarbons?

A

Exothermic- lots of energy released.

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15
Q

Why are shorter hydrocarbons better fuels?

A

Because they are more volatile and flammable due to their low boiling points.
- Require less oxygen to burn completely - more efficient and cleaner.

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16
Q

What does the properties of hydrocarbons depend on?

A

Length of the carbon chains.

17
Q

Are hydrocarbons a homologous series?

A

No. Alkanes and alkanes are.

18
Q

What is crude oil?

A
  • Fossil fuel.
  • Get from deep underground.
  • Mixture of lots of different compounds which nearly all of then are hydrocarbons (alkanes are more common).
19
Q

How was crude oil formed?

A
  • Remains of dead plants and animals mainly plankton.
  • Animals dies millions of year ago and buried in the mud.
  • High pressures and temperatures underground turned the organic biomass into crude oil.
20
Q

why is crude oil considered finite?

A

Can’t be replenished on a human timescale as it takes a long time to form so if we continue to extract and use it at the current rapid rate it will run out.

21
Q

Why do we separate the hydrocarbons in the mixture crude oil?

A

They each have different properties so well use them for different things.

22
Q

Why does fractional distillation work for separating different compounds in crude oil?

A

Each of the compounds has a different boiling point.

23
Q

Steps of fractional distillation of crude oil?

A

1)Feed oil into chamber and heat until most of it has turned into a gas.
2)Pass gaseous mixture into a fractionating column (hot at the bottom and cool at the top).
3) Gasses will rise up the column but condense into a liquid when they reach reigon with a lower temperature than their boiling point.
4) Longer chain hydrocarbons -> highest BP -> condense in the hotter regions near bottom of fractionating column.
5) Shorter chain -> lower BP -> condense in cooler regions near top.
6) Really shorter ones stay as a gas the entire time.

24
Q

What are the uses of longer chain hydrocarbons (that are poor fuels)?

A

-Used for something else.
-Broken down into smaller hydrocarbons in cracking.

25
What are petrochemicals?
All the substances we get from crude oil.
26
What are the uses of petrochemicals?
Feedstock (raw materials) for the petrochemical industry. Making things such as: solvents, lubricants, polymers and detergents.
27
What happens generally in the process of cracking?
Longer chain hydrocarbons (less useful) broken down into shorter chain and more useful hydrocarbons that are more flammable.
28
What type of reaction is cracking? What does it mean?
A thermal decomposition reaction- using heat to break down molecules.
29
What are the two main methods of cracking?
- Catalytic cracking - Steam cracking
30
Steps of catalytic cracking?
1) Heat long chain hydrocarbons to vaporise them. 2) Pass the hydrocarbon vapour over hot powdered aluminium oxide (the catalyst). 3)As long chain hydrocarbons come into contact with catalyst they split apart into two smaller hydrocarbons.
31
What are the steps of steam cracking?
1) Heat long chain hydrocarbons until vaporised. 2) Mix hydrocarbon vapour with steam and heat to a very high temprature. 3) Long hydrocarbon chains split into shorter ones.
32
What does cracking produce (give formula)?
Long chain alkANE —> shorter alkANE + alkENE
33
What makes alkENEs unsaturated?
When the longer chain alkanes undergo cracking and thermal decomposition, there isn’t enough hydrogen left for both the alkane and alkene produced to be saturated, so the alkene forms a double carbon bond instead.
34
What are alkENEs used for?
- Produce polymers. - Starting materials for producing other chemicals.
35
What are the key “traits” of alkENEs (PUR)?
- Unsaturated - More reactive than alkANEs (due to the double carbon bond?) - Can be added together to make polymers.
36
What is the test for alkENEs?
- Bromine water is an orange solution. - Add bromine water to solution of alkENEs. - AlkENEs will react with bromine to de-colourise the solution. - Posistive test: colourless solution.
37
Why can we make polymers out of alkENEs?
Because the double bonds can break to form two more bonds.
38
Why do alkANEs not de-colourise bromine water?
Because alkanes are not reactive enough to react with bromine water. (No double carbon bonds).