enthalpy definitions Flashcards

(17 cards)

1
Q

Enthalpy change of reaction is the

A

enthalpy
change when the number of moles of reactants as specified in the
balanced equation react together

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2
Q

The standard enthalpy change of formation of a compound is the

A

enthalpy change when 1 mole of the compound is formed from
its elements under standard conditions (298K and 100kpa), all
reactants and products being in their standard states

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3
Q

The standard enthalpy of combustion of a substance is defined as

A

the enthalpy change that occurs when one mole of a substance is
combusted completely in oxygen under standard conditions.
(298K and 100kPa), all reactants and products being in their
standard states

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4
Q

The standard enthalpy change of neutralisation is the

A

enthalpy change when solutions of an acid and an alkali react together under standard conditions to produce 1 mole of water.

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5
Q

Enthalpy of atomisation

A

The enthalpy of atomisation of an element is the enthalpy change
when 1 mole of gaseous atoms is formed from the element in its standard state

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6
Q

Enthalpy of sublimation will be the same as

A

the enthalpy of atomisation

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7
Q

First Ionisation enthalpy

A

enthalpy change required to remove 1 mole of electrons from 1 mole
of gaseous atoms to form 1 mole of gaseous ions with a +1 charge

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8
Q

Second Ionisation enthalpy

A

enthalpy change to remove 1 mole of electrons from one mole
of gaseous 1+ ions to produces one mole of gaseous 2+ ions.

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9
Q

First Ionisation enthalpy example

A

Mg (g) -> Mg+(g) + e-

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10
Q

Second Ionisation enthalpy example

A

Mg+(g) -> Mg 2+ (g) + e-

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11
Q

First Electron affinity

A

enthalpy change that occurs when 1 mole of gaseous atoms gain 1 mole of electrons to form 1 mole of gaseous ions with a 1-
charge

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12
Q

First Electron affinity example

A

O (g) + e- -> O- (g)

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13
Q

second electron affinity

A

enthalpy change when one mole of gaseous 1- ions gains one
electron per ion to produce gaseous 2- ions

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14
Q

second electron affinity example

A

O –(g) + e- -> O2- (g)

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15
Q

The Lattice Enthalpy is the

A

standard enthalpy change when 1 mole of an ionic crystal lattice is formed from its constituent ions in gaseous form.

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16
Q

Enthalpy of Hydration

A

Enthalpy change when one mole of gaseous ions become 1 mole of aqueous ions

17
Q

enthalpy change of solution

A

enthalpy change when 1 mole of solute dissolves completely in a solvent, water